Quantifying the barrier for the movement of cyclobis(paraquat-p-phenylene) over the dication of monopyrrolotetrathiafulvalene

Autor: Rikke Kristensen, Mathias S. Neumann, Sissel S. Andersen, Paul C. Stein, Amar H. Flood, Jan O. Jeppesen

Publikováno v: Kristensen, R, Neumann, M S, Andersen, S S, Stein, P C, Flood, A H & Jeppesen, J O 2022, ' Quantifying the barrier for the movement of cyclobis(paraquat-p-phenylene) over the dication of monopyrrolotetrathiafulvalene ', Organic & Biomolecular Chemistry, vol. 20, no. 11, pp. 2233-2248 . https://doi.org/10.1039/d1ob02263f

A bistable [2]pseudorotaxane 1⊂CBPQT·4PF6 and a bistable [2]rotaxane 2·4PF6 have been synthesised to measure the height of an electrostatic barrier produced by double molecular oxidation (0 to +2). Both systems have monopyrrolotetrathiafulvalene

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::59dfa69f08ba6054324f7e3b819aed68
https://doi.org/10.1039/d1ob02263f

Mechanistic studies of isomeric [2]rotaxanes consisting of two different tetrathiafulvalene units reveal that the movement of cyclobis(paraquat-p-phenylene) can be controlled.

Autor: Jensen, Sofie K., Neumann, Mathias S., Frederiksen, Rikke, Skavenborg, Mathias L., Larsen, Mads C., Wessel, Stinne E., Jeppesen, Jan O.

Publikováno v: Chemical Science; 11/21/2023, Vol. 14 Issue 43, p12366-12378, 13p

Contents list.

Publikováno v: Chemical Communications; 5/25/2023, Vol. 59 Issue 42, p6263-6271, 9p

Quantifying the barrier for the movement of cyclobis(paraquat-p-phenylene) over the dication of monopyrrolotetrathiafulvalene.

Autor: Kristensen, Rikke, Neumann, Mathias S., Andersen, Sissel S., Stein, Paul C., Flood, Amar H., Jeppesen, Jan O.

Publikováno v: Organic & Biomolecular Chemistry; 3/21/2022, Vol. 20 Issue 11, p2233-2248, 16p