Metal phosphate catalyzed dehydration of sorbitol under hydrothermal conditions

Autor: Wolfgang F. Hoelderich, Mathias Ibert, Oana Alice Rusu, Herve Wyart

Publikováno v: Applied Catalysis B: Environmental. :139-149

The intention of this work is to develop a heterogeneously catalyzed, environmentally friendly and sustainable process for the production of isosorbide by dehydration of sorbitol. The presence of the heterogeneous catalyst BP in the batch reactor had

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7ae79558087c8da06464631b73aa6098
https://doi.org/10.1016/j.apcatb.2015.03.033

Palladium-catalyzed hydroesterification of olefins with isosorbide in standard and Br?nsted acidic ionic liquids

Autor: Mathias Ibert, André Mortreux, Eric Monflier, Jérôme Boulanger, Thomas Chenal, Mathieu Sauthier, Anne Ponchel, Bastien Léger, Adeline Seingeot, Romain Pruvost

Publikováno v: Catalysis Communications
Catalysis Communications, Elsevier, 2015, Catalysis Communications, 69, pp.143-146. ⟨10.1016/j.catcom.2015.06.008⟩
Catalysis Communications, 2015, Catalysis Communications, 69, pp.143-146. ⟨10.1016/j.catcom.2015.06.008⟩

The palladium catalyzed hydroesterification of 1-octene with isosorbide was studied in standard and Bronsted acidic ionic liquids as reaction media. High conversions and selectivities towards the targeted isosorbide diesters have been achieved by usi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fb9f37a6943b6cb52ab317f54c14aab5
https://hal.archives-ouvertes.fr/hal-01685315

Synthesis of 1,4:3,6-Dianhydrohexitols Diesters from the Palladium-Catalyzed Hydroesterification Reaction

Autor: Bastien Léger, Anne Ponchel, Jérôme Boulanger, Thomas Chenal, Eric Monflier, Mathieu Sauthier, André Mortreux, Romain Pruvost, Mathias Ibert

Publikováno v: ChemSusChem
ChemSusChem, 2014, 7 (11), pp.3157-3163. ⟨10.1002/cssc.201402584⟩
ChemSusChem, ChemPubSoc Europe/Wiley, 2014, 7 (11), pp.3157-3163. ⟨10.1002/cssc.201402584⟩

The hydroesterification of alpha olefins has been used to synthesize diesters from bio-based secondary diols: isosorbide, isomannide, and isoidide. The reaction was promoted by 0.2% palladium catalyst generated in situ from palladium acetate/tripheny

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ce8933c6bc0fe6c1dad8f66e5a880d4c
https://hal.science/hal-01681334

Copper-Catalyzed vs Thermal Step Growth Polymerization of Starch-Derived α-Azide−ω-Alkyne Dianhydrohexitol Stereoisomers: To Click or Not To Click?

Autor: Mathias Ibert, Etienne Fleury, Jean-Pierre Pascault, Patrick Fuertes, Céline Besset, Eric Drockenmuller, Sandra Binauld, Julien Bernard

Publikováno v: Macromolecules. 43:17-19

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::31aa2545322eab76089fcf1e03b772b9
https://doi.org/10.1021/ma9024784

Evidence of benzilic rearrangement during the electrochemical oxidation of D-glucose to D-glucaric acid

Autor: Nabyl Merbouh, Mathias Ibert, Patrick Fuertes, Francis Marsais, Christian Feasson

Publikováno v: Carbohydrate Research
Carbohydrate Research, Elsevier, 2011, 346 (4), pp.512-518. ⟨10.1016/j.carres.2010.12.017⟩

International audience; During the course of the 2,2,6,6-tetramethyl-1-piperidinyloxy free radical-catalyzed electrochemical oxidation of D-glucose to D-glucaric acid a new side-product was observed. This compound was isolated and identified as a tri

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cbb85d9387c61175836a44ab9f2cd182
https://hal.archives-ouvertes.fr/hal-00992147