Zobrazeno 1 - 10
of 13
pro vyhledávání: '"Massimo Scicchitano"'
Publikováno v:
Surface Coatings International. 82:384-389
A series of fluorinated coatings suitable for low temperature curing can be obtained by the proper combination of fluoropolyether macromers with the cyclic trimers of HDI and IPDI. In all cases they are characterised by general excellent surface prop
Autor:
Luigi Costa, Claudio Tonelli, Massimo Scicchitano, J. Scheirs, Stefano Turri, Giovanni Camino
Publikováno v:
Polymer Degradation and Stability. 62:327-336
Three functionalized perfluorinated polyethers (PFPE) were exposed to UV light ( λ >300 nm) in air, and chemical changes recorded by FTIR and 1 H, 13 C, 19 F NMR spectrometry. One of the derivatives (ZTET), end-capped by an hydrogenated ether segmen
Publikováno v:
Progress in Organic Coatings. 32:205-213
Hydroxy bifunctional fluoropolyether oligomers (ZDOL) are presented suitable for use as resins or for the preparation of polyurethane, polyester and polyether higher OH functionality resins. The synthesis procedures are described and discussed, and t
Autor:
J. Scheirs, Stefano Turri, Massimo Scicchitano, Luigi Costa, Giovanni Camino, Claudio Tonelli
Publikováno v:
Polymer Degradation and Stability. 56:239-253
The photooxidation of a series of functionalized perfluorinated polyethers (PFPEs) was studied by FTIR, 1H- and 19F-NMR with progressive exposure to UV light (λ > 300nm). The objective of this work is to build an understanding of the UV stability of
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 34:3263-3275
Different synthetic methods for the preparation of polyfunctional fluorinated oligomers were explored and the results compared. Fluoropolyether macromonomers bearing epoxy, allyl, and polyhydroxy end groups were synthesized and spectroscopically char
Publikováno v:
Angewandte Makromolekulare Chemie. 236:111-127
New fluoropolyether polyolic resins are presented suitable to be cured with conventional hardeners as polyisocyanates or melamines. These resins are prepared by addition of fluoropolyether macrodiols (Fomblin® ZDOLTX) of various molecular weights to
Publikováno v:
Journal of Applied Polymer Science. 59:311-327
New fluorinated thermoplastic elastomers (FTE) with perfluoropolyether (PFPE) blocks have been synthesized by reacting a fluorinated macrodiol with aromatic diisocyanates in the presence of a solvent, followed by subsequent chain extension with low m
Publikováno v:
European Polymer Journal. 31:1227-1233
Glass transition temperatures, specific volumes and viscosities of concentrated solutions of two diolic (functionalized) perfluoropolyoxyalkylene oligomers in various solvents are reported. It is shown that polar solvents, generally considered poor o
Publikováno v:
European Polymer Journal. 31:1235-1242
Viscosities and densities of two low molecular weight perfluoropolyoxyalkylene diols in 11 polar solvents are analysed. The specific volume-concentration behaviour shows the presence of an excess mixing volume common to all the solvents tested. Plots
Publikováno v:
Angewandte Makromolekulare Chemie. 231:47-60
Six oligomeric polyols having a common perfluoropolyether chain end-capped by different hydrogenated segments containing hydroxylic groups were synthesized and their properties described. The general scheme for the synthesis of these polyols involved