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pro vyhledávání: '"Masashi Ikawa"'
Publikováno v:
Journal of the American Chemical Society. 133:18018-18021
Pyridines, which comprise one of the most important classes of the six-membered heterocyclic compounds, are widely distributed in nature, and the transition-metal-catalyzed [2 + 2 + 2] cycloaddition reaction of two alkynes and a nitrile is one of the
Publikováno v:
Organometallics. 30:2765-2774
The use of Me2AlCl as an additive was found to allow the oxidative addition of the Ar–CN bond in 2-(2-methylallyl)benzonitrile on nickel(0) in the presence of PnBu3, giving a trans-arylnickelcyanide complex. In contrast, in the presence of PCy3, th
Publikováno v:
ChemInform. 43
The title reaction allows an efficient and regioselective access to a wide range of pyridines.
Publikováno v:
Journal of the American Chemical Society. 130(39)
A catalyst system derived from nickel and cocatalytic AlMe2Cl effects the intramolecular arylcyanation of alkenes. The reaction takes place in an exclusive exo-dig manner to give a wide range of nitriles having a benzylic quaternary carbon in good yi