Zobrazeno 1 - 10 of 457 pro vyhledávání: '"Masanobu Hidai"'
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Synthesis and Reactivity of Tungsten− and Molybdenum−Dinitrogen Complexes Bearing Ferrocenyldiphosphines toward Protonolysis
Autor: Masahiro Yuki, Yoshihiro Miyake, Yoshiaki Nishibayashi, Masanobu Hidai, Issei Wakiji
Publikováno v: Organometallics. 27:3947-3953
Novel tungsten− and molybdenum−dinitrogen complexes bearing 1,1′-bis(diethylphosphino)ferrocenes as auxiliary ligands have been prepared and characterized crystallographically. Reactions of these complexes with an excess amount of sulfuric acid
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c67e3548aaa7c9432069c77968274f7a
https://doi.org/10.1021/om800327j
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3
DFT Study on Chemical N2 Fixation by Using a Cubane-Type RuIr3S4 Cluster: Energy Profile for Binding and Reduction of N2 to Ammonia via Ru−N−NHx (x = 1−3) Intermediates with Unique Structures
Autor: Hidetake Seino, Hiromasa Tanaka, Yasushi Mizobe, Hiroyuki Mori, Kazunari Yoshizawa, Masanobu Hidai
Publikováno v: Journal of the American Chemical Society. 130:9037-9047
The N-N bond activation of the dinitrogen ligand in the cubane-type mixed-metal sulfido cluster, [(Cp*Ir) 3{Ru(tmeda)(N 2)}(mu 3-S) 4] (tmeda = Me 2NCH 2CH 2NMe 2), is investigated by using DFT calculations at the B3LYP level of theory. The elongated
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e23a4e87f02d167d2f9f366cb2240620
https://doi.org/10.1021/ja8009567
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5
Mixed-Metal Sulfido Clusters Containing Noble Metals and Group 15 Metals. Stepwise Construction of Bimetallic and Trimetallic Ru2MS2 (M = Sb, Bi), Ru2PdSbS2, and Ru2Pd2SbS2 Cores
Autor: Takahiko Amitsuka, Hidetake Seino, Masanobu Hidai, Yasushi Mizobe
Publikováno v: Organometallics. 25:3034-3039
By starting from a diruthenium bis(μ-hydrosulfido) complex [(Cp°RuCl)2(μ-SH)2] (1; Cp° = η5-C5Me4Et), a series of new mixed-metal sulfur clusters containing both noble metals and group 15 metals have been synthesized. Thus, 1 was allowed to reac
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::366be1f4fb4add673d705fe146da47de
https://doi.org/10.1021/om060071s
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6
Research inspired by the chemistry of nitrogenase — Novel metal complexes and their reactivity toward dinitrogen, nitriles, and alkynes
Autor: Yasushi Mizobe, Masanobu Hidai
Publikováno v: Canadian Journal of Chemistry. 83:358-374
Summarized here are our continuous studies of the last three decades concerning syntheses of new types of complexes learned from nitrogenase and their reactivites toward dinitrogen, nitriles, and alkynes. For Mo and W dinitrogen complexes with tertia
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::7e81e5636076119221ac55977e54bc77
https://doi.org/10.1139/v05-016
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7
Preparation and structures of the cluster dimers consisting of Rh2Mo2S4 single-cubane units connected by two bidentate N-donor ligands
Autor: Tomoko Fujimura, Hidetake Seino, Masanobu Hidai, Yasushi Mizobe
Publikováno v: Inorganica Chimica Acta. 358:2449-2453
Reactions of a single-cubane cluster [{Rh(cod)} 2 {MoCl(dtc)} 2 (μ 3 -S) 4 ] (cod = 1,5-cyclooctadiene, dtc = diethyldithiocarbamate) with 1 equiv. of L (L = pyrazine, 4,4′-bipyridyl, trans -1,2-bis(4-pyridyl)ethylene) in the presence of 2 equiv.
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0b20cd52549ac65502bdc07d949c4627
https://doi.org/10.1016/j.ica.2005.01.021
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8
The C O and C S bond cleavage in carbon dioxide and tolyl isothiocyanate by reactions with the Mo(0) tetraphosphine complex [Mo{meso-o-C6H4(PPhCH2CH2PPh2)2}(Ph2PCH2CH2PPh2)]
Autor: Hidetake Seino, Takeshi Ohnishi, Masanobu Hidai, Yasushi Mizobe
Publikováno v: Journal of Organometallic Chemistry. 690:1140-1146
A Mo(0) complex containing a new tetraphosphine ligand [Mo( P 4 )(dppe)] ( 1 ; P 4 = meso-o -C 6 H 4 (PPhCH 2 CH 2 PPh 2 ) 2 , dppe = Ph 2 PCH 2 CH 2 PPh 2 ) reacted with CO 2 (1 atm) at 60 °C in benzene to give a Mo(0) carbonyl complex fac -[Mo(CO)
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e5967d127e76375c9a5dd06a8891c131
https://doi.org/10.1016/j.jorganchem.2004.11.020
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9
Synthesis and X-ray structure of the new Mo diselenido complex with hydrotris(pyrazolyl)borate coligand [Et4N][TpMo(CO)2(η2-Se2)]
Autor: Masanobu Hidai, Yasushi Mizobe, Shoken Nagao, Hidetake Seino
Publikováno v: Inorganica Chimica Acta. 357:4618-4621
Reaction of the Mo(0) complex [Et4N][TpMo(CO)3] (Tp = hydrotris(pyrazol-1-yl)borate) with red Se in MeCN at 50 °C afforded the Mo(II) diselenido complex [Et4N][TpMo(CO)2(η2-Se2)] (2), whose structure has been determined in detail by the single-crys
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::793228d4de9bf4f26bcadf54a45944ca
https://doi.org/10.1016/j.ica.2004.06.035
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10
Ruthenium-Catalyzed Allylation of Aromatic Compounds and Allylic Ether Formation
Autor: Gen Onodera, Masashi Yamanashi, Sakae Uemura, Masanobu Hidai, Hiroaki Imajima, Yoshiaki Nishibayashi
Publikováno v: Organometallics. 23:5841-5848
Ruthenium-catalyzed allylation of aromatic compounds such as benzene, toluene, p-xylene, anisole, phenol, furans, and thiophenes with allylic alcohol derivatives gives the corresponding allylated products in good to high yields with a high regioselec
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cc6981fb6c5cb7e363a4fd06611a74a8
https://doi.org/10.1021/om049358k
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