Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Masakatsu Shimoda"'
Autor:
Masahiro Kako, Kunio Mochida, Masanori Yasui, Seiji Kakuma, Yasuhiro Nakadaira, Matsumoto Fuyuhiko, Fujiko Iwasaki, Masakatsu Shimoda, Haruhiko Komoriya, Masao Yashikawa
Publikováno v:
Bulletin of the Chemical Society of Japan. 73:1403-1408
By X-ray crystallographic analysis, the molecular structure of 3,4,7,8-tetragermacycloocta-1,5-diyne 1b has been established to be planar and quite similar to that of silicon analog 3,4,7,8-tetrasilacycloocta-1,5-diyne 1a. The detailed comparison of
Autor:
Hisao Kurosu, Kunio Mochida, Kojima Akio, Yoshida Harada, Matsumoto Fuyuhiko, Masakatsu Shimoda, Rieko Hata, Masao Yoshikawa, Shigeru Masuda
Publikováno v:
Polyhedron. 15:3027-3032
The ionization potentials of gaseous and solid oligogermanes and polygermanes were measured in the 5.31–8.60 eV regions, and were assigned to ionizations from the germanium framework, by ultraviolet photoelectron spectroscopy. The values of ionizat
Publikováno v:
Polyhedron. 13:3039-3040
The first ionization potentials of oligogermanes and polygermanes were obtained in the 5.31–5.95 eV region using a very simple but useful low energy photoelectron emission measurement in air.
Publikováno v:
Chemistry Letters. 17:535-538
Diphenylselenogermanes are prepared for the first time in 32–89% yield by the reaction between sodium benzeneselenolate and dihalogermanes (halogen=Cl or Br). The X-ray structure of 1,1-diphenylseleno-1-germacyclopentane has been determined.
Publikováno v:
Chemistry Letters. 18:1373-1376
The steric compression effect (γ-effect) of γ-carbon on 77Se chemical shift in mono- and diselenogermanes has been first evaluated by 77Se NMR spectroscopy. The γ-gauche effect falls in the range between −59.1 and −13.6 ppm (upfield shift).
Publikováno v:
ChemInform. 19
Diphenylselenogermanes are prepared for the first time in 32–89% yield by the reaction between sodium benzeneselenolate and dihalogermanes (halogen=Cl or Br). The X-ray structure of 1,1-diphenylseleno-1-germacyclopentane has been determined.
Autor:
Masakatsu Shimoda, Katsumi Tanaka, Keiichiro Ogawa, Shuji Tomoda, Yoshito Takeuchi, Hiroshi Suzuki
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :7
Molecular mechanics calculations in germacyclohexane and methyl-substituted germacyclohexanes reveals that (i) the ring is flattened around the germanium and that (ii) a methyl group on germanium has a slight preference for the axial conformation rat
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :1304
An X-ray crystallographic analysis and dynamic 1H n.m.r. study have shown that the title compound exists in a symmetrical 2,5-twist-boat conformation both in the solid state and in solution; an unusually high barrier for interconversion between the t
Autor:
Kinichi Obi, Yoshito Takeuchi, Koichi Honda, Shuji Tomoda, Yoshizumi Kajii, Masakatsu Shimoda, Lkuzo Tanaka
Publikováno v:
Journal of the Chemical Society, Chemical Communications. :910
Dimethylgermylene (1), generated from a new precursor dimethylbis(phenylseleno)germane (2), has been observed as a transient species by time-resolved laser flash photolysis at room temperature.
Autor:
Kunio Mochida, Rieko Hata, Masakatsu Shimoda, Fuyuhiko Matsumoto, Hisao Kurosu, Akio Kojima, Masao Yoshikawa, Shigeru Masuda, Yoshida Harada
Publikováno v:
In Polyhedron 1996 15(18):3027-3032