Zobrazeno 1 - 10
of 429
pro vyhledávání: '"Masahito Ochiai"'
Autor:
Kazunori Miyamoto, Shodai Narita, Yui Masumoto, Takahiro Hashishin, Taisei Osawa, Mutsumi Kimura, Masahito Ochiai, Masanobu Uchiyama
Publikováno v:
Nature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
Diatomic carbon (C2) is historically an elusive chemical species, considered to require high physical energy for its generation. Here, the authors describe the first room-temperature chemical synthesis of C2 and present experimental evidence for its
Externí odkaz:
https://doaj.org/article/67317a9a45f645f189f2bed624424990
Autor:
Kazunori Miyamoto, Shodai Narita, Yui Masumoto, Takahiro Hashishin, Taisei Osawa, Mutsumi Kimura, Masahito Ochiai, Masanobu Uchiyama
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-3 (2021)
Externí odkaz:
https://doaj.org/article/902e99450d66407092417e0cc6a28cac
Publikováno v:
Journal of Synthetic Organic Chemistry, Japan. 81:416-427
Autor:
Kazunori Miyamoto, Shunsuke Tsuji, Motoo Shiro, Masanobu Uchiyama, Taisei Takagi, Motomichi Saito, Masahito Ochiai
Publikováno v:
Journal of the American Chemical Society. 143:9327-9331
We present the first synthesis of air/moisture-stable λ3-bromanes (9 and 10) by using a cyclic 1,2-benzbromoxol-3-one (BBX) strategy. X-ray crystallography and NMR and IR spectroscopy of N-triflylimino-λ3-bromane (12) revealed that the bromine(III)
Autor:
Takuya Matsumoto, Hikaru Fujita, Kazuhito Hioki, Hiroshi Hagiyama, Masahito Ochiai, Kanetsugu Kuribayashi, Munetaka Kunishima
Publikováno v:
Organic & Biomolecular Chemistry. 19:3825-3828
A series of (E)-α-silyl-β-alkoxyvinyl-λ3-iodanes was synthesized from iodosylbenzene, BF3–ether complexes, and terminal ethynylsilanes. The combined use of BF3–OiPr2 and benzyl ethers of primary alcohols (ROBn) allows the chemoselective transf
Autor:
Mutsumi Kimura, Yui Masumoto, Taisei Osawa, Masanobu Uchiyama, Kazunori Miyamoto, Shodai Narita, Takahiro Hashishin, Masahito Ochiai
Publikováno v:
Nature Communications, Vol 11, Iss 1, Pp 1-7 (2020)
Diatomic carbon (C2) is historically an elusive chemical species. It has long been believed that the generation of C2 requires extremely high physical energy, such as an electric carbon arc or multiple photon excitation, and so it has been the genera
Autor:
Masanobu Uchiyama, Taisei Osawa, Takahiro Hashishin, Kazunori Miyamoto, Masahito Ochiai, Mutsumi Kimura, Shodai Narita, Yui Masumoto
Publikováno v:
Nature Communications, Vol 12, Iss 1, Pp 1-3 (2021)
Publikováno v:
ARKIVOC, Vol 2003, Iss 6, Pp 43-48 (2003)
Externí odkaz:
https://doaj.org/article/129d89c2f19043b0ae7f46280fc8792f
Autor:
Kazunori, Miyamoto, Shodai, Narita, Yui, Masumoto, Takahiro, Hashishin, Taisei, Osawa, Mutsumi, Kimura, Masahito, Ochiai, Masanobu, Uchiyama
Publikováno v:
Nature Communications
Autor:
Keiichi Hirano, Masahito Ochiai, Masanobu Uchiyama, Kazunori Miyamoto, Takuto Iuchi, Yui Masumoto, Tatsuo Saito, Chao Wang
Publikováno v:
The Journal of Organic Chemistry. 83:289-295
Because of its hyper-leaving ability, as well as its strong oxidizing ability, diaryl(triflato)-λ3-iodane transfers one of the aryl groups to iodoarenes simply upon gentle heating (>85 °C) in nonpolar solvents. We have performed an in-depth mechani