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pro vyhledávání: '"Masahisa Kakiuchi"'
Autor:
Masahisa Kakiuchi
Publikováno v:
Zeitschrift für Naturforschung A. 62:721-728
The D/H ratio of hydrogen gas in equilibrium with aqueous alkaline earth (Mg, Ca, Sr or Ba) chloride solutions measured at 25◦C using a hydrophobic platinum catalyst, was found to be higher than the D/H ratio equilibrated with the applied pure wate
Autor:
Masahisa Kakiuchi
Publikováno v:
Bulletin of the Chemical Society of Japan. 74:2011-2017
Based on the results of hydrogen isotope fractionation in aqueous alkali halide solutions at 25 °C, reported in previous papers, the hydrogen isotope effect between water molecules hydrated to a cation or an anion and bulk water molecules is estimat
Publikováno v:
GEOCHEMICAL JOURNAL. 35:285-293
The D/H fractionation factor between crystal water in copper chloride dihydrate and water vapor was calculated from Raman spectral data for single crystals of CuCl22H2O and CuCl22D2O based on statistical mechanics. Single crystals of CuCl22H2O and Cu
Autor:
Masahisa Kakiuchi
Publikováno v:
GEOCHEMICAL JOURNAL. 35:277-283
The D/H fractionation factors between the crystal water of copper chloride dihydrate and a saturated aqueous solution of copper(II) chloride, αCW-st.sol, and between the saturated aqueous solution and water vapor, αst.sol-V, were experimentally det
Autor:
Masahisa Kakiuchi
Publikováno v:
Geochimica et Cosmochimica Acta. 64:1485-1492
The distribution of isotopic water molecules, H2O, HDO, and D2O, in vapor and liquid phases in pure water and aqueous solution systems is related to the D/H fractionation factor between liquid and vapor phases, αL-V, and the vapor pressure ratio bet
Autor:
Masahisa Kakiuchi
Publikováno v:
RADIOISOTOPES. 48:79-86
Autor:
Masahisa Kakiuchi
Publikováno v:
Zeitschrift für Naturforschung A. 52:811-820
The D/H ratios of hydrogen gas in equilibrium with aqueous alkali halide solutions were deter-mined at 25 °C, using a hydrophobic platinum catalyst. The hydrogen isotope effect between the solution and pure water changes linearly with the molality o
Autor:
Masahisa Kakiuchi
Publikováno v:
Journal of Solution Chemistry. 23:1073-1087
The D/H ratios of hydrogen gas in equilibrium with aqueous sodium chloride solutions of 2, 4 and 6 molalities were determined within the range 10 to 95°C, using a hydrophobic platinum catalyst. With each of the different sodium chloride concentratio
Publikováno v:
International Journal of Radiation Applications and Instrumentation. Part A. Applied Radiation and Isotopes. 42:741-748
For the purpose of improving the accuracy and precision of tritium measurements in natural waters, this paper proposes a new method for the estimation of tritium concentration after electrolytic enrichment. The proposed method was based on the fact t
Autor:
Masahisa Kakiuchi
Publikováno v:
Isotopes in environmental and health studies. 42(3)
The hydrogen isotopic fractionation factors between the crystal water (CW) in crystalline hydrates and the saturated aqueous solution of cobalt dichloride, alphaCW-st.sol, were experimentally determined in the temperature range from 10 to 55 degrees