Zobrazeno 1 - 10
of 847
pro vyhledávání: '"Mary F. Mahon"'
Autor:
Kyle G. Pearce, Han-Ying Liu, Samuel E. Neale, Hattie M. Goff, Mary F. Mahon, Claire L. McMullin, Michael S. Hill
Publikováno v:
Nature Communications, Vol 14, Iss 1, Pp 1-5 (2023)
Abstract Counter to synthetic convention and expectation provided by the relevant standard reduction potentials, the chloroberyllate, [{SiNDipp}BeClLi]2 [{SiNDipp} = {CH2SiMe2N(Dipp)}2; Dipp = 2,6-i-Pr2C6H3)], reacts with the group 1 elements (M = Na
Externí odkaz:
https://doaj.org/article/bf8aa694578d45db8b74eaf53ae133dc
Publikováno v:
Advanced Science, Vol 10, Iss 31, Pp n/a-n/a (2023)
Abstract The dimeric β‐diketiminato calcium hydride, [(DippBDI)CaH]2 (DippBDI = HC{(Me)CN‐2,6‐i‐Pr2C6H3}2), reacts with ortho‐, meta‐ or para‐tolyl mercuric compounds to afford hydridoarylcalcium compounds, [(DippBDI)2Ca2(μ‐H)(μ‐
Externí odkaz:
https://doaj.org/article/b02a811e760b4b2e92d1a1bd02303a84
Publikováno v:
ChemistryOpen, Vol 9, Iss 11, Pp 1113-1122 (2020)
Abstract A microwave‐based methodology facilitates reaction of 2‐aminophenylketones with cyclic ketones to form a quinoline scaffold. Syntheses of amido‐ and amino‐linked 17β‐hydroxysteroid dehydrogenase type 3 inhibitors with a benzopheno
Externí odkaz:
https://doaj.org/article/6dd4e0b176994deb903ddea9352755b1
Autor:
Rex S. C. Charman, Thomas M. Horsley Downie, Thomas H. Jerome, Mary F. Mahon, David J. Liptrot
Publikováno v:
Inorganics, Vol 10, Iss 9, p 135 (2022)
Frustrated Lewis pairs (FLPs) have evolved from a revolutionary concept to widely applied catalysts. We recently reported the ring-expanded N-heterocyclic carbene supported copper(I) boryliminomethanide, (6-Dipp)CuC(=NtBu)Bpin and noted it reacted wi
Externí odkaz:
https://doaj.org/article/59097b4227354c32b40aafb48b089410
Publikováno v:
Chemical Science. 14:2866-2876
The C–Al bond of [{SiNDipp}Al–Cu(NHCiPr)] reacts sequentially with three equivalents of terminal alkyne to provide cuprous (hydrido)(alkynyl)aluminate, (E-alkenyl)(alkynyl)aluminate and bis(alkynyl)aluminate derivatives.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::aaba3274e92ecad77ce26192d56fc68d
https://doi.org/10.1039/d3sc00240c
https://doi.org/10.1039/d3sc00240c
Autor:
Ross A. Jackson, Aidan J. R. Matthews, Petra Vasko, Mary F. Mahon, Jamie Hicks, David J. Liptrot
Publikováno v:
Chemical Communications. 59:5277-5280
The potassium aluminyl, K2[Al{N(Dipp)SiMe3}2]2 has been synthesised. Reaction with [HC{(CH3)C(Dipp)N}2]MgI(OEt2) forms [HC{(CH3)C(Dipp)N}2]MgAl{N(Dipp)SiMe3}2, a monomeric, acyclic, magnesium aluminyl complex.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::d2b087edc821c1b5a04d9fb088f955b8
https://doi.org/10.1039/d3cc01317k
https://doi.org/10.1039/d3cc01317k
Publikováno v:
Pearce, K G, Hill, M S & Mahon, M F 2023, ' Beryllium-centred C-H Activation of Benzene ', Chemical communications (Cambridge, England), vol. 59, no. 11, pp. 1453-1456 . https://doi.org/10.1039/D2CC06702A
Reaction of BeCl2 with the dilithium diamide, [{SiNDipp}Li2] ({SiNDipp} = {CH2SiMe2NDipp}2), provides the dimeric chloroberyllate, [{SiNDippBeCl)Li]2, en route to the 2-coordinate beryllium amide, [SiNDippBe]. Lithium or sodium reduction of [SiNDippB
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c7a4dff6cb56ef140e6b9c0de8e3aac3
https://doi.org/10.1039/d2cc06702a
https://doi.org/10.1039/d2cc06702a
Autor:
Han-Ying Liu, Samuel E. Neale, Michael S. Hill, Mary F. Mahon, Claire L. McMullin, Benjamin L. Morrison
Publikováno v:
Chemical Communications. 59:3846-3849
[{SiNDipp}MgNa]2 ({SiNDipp} = {CH2SiMe2N(Dipp)}2; Dipp = 2,6-i-Pr2C6H3) reacts directly with H2 in a process, which computational studies suggest, is dictated by the frontier MOs of both H2 and the low oxidation state s-block assembly.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::057488f5b90f4269444cb6c1f4f3b1e8
https://doi.org/10.1039/d3cc00710c
https://doi.org/10.1039/d3cc00710c
Autor:
Nigel Vicker, Helen V. Bailey, Joanna M. Day, Mary F. Mahon, Andrew Smith, Helena J. Tutill, Atul Purohit, Barry V. L. Potter
Publikováno v:
Molecules, Vol 26, Iss 23, p 7166 (2021)
17β-Hydroxysteroid dehydrogenase type 3 (17β-HSD3) is expressed at high levels in testes and seminal vesicles; it is also present in prostate tissue and involved in gonadal and non-gonadal testosterone biosynthesis. The enzyme is membrane-bound, an
Externí odkaz:
https://doaj.org/article/ce51c043edab4dc4bcbf6ec11880d2fa
Autor:
Anne-Frédérique Pécharman, Annie L. Colebatch, Michael S. Hill, Claire L. McMullin, Mary F. Mahon, Catherine Weetman
Publikováno v:
Nature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
Organoboranes are widely employed in organic synthesis and typically are prepared using electrophilic boron sources. Here the authors report a route to nucleophilic boryl anions via organomagnesium-driven cleavage of boron-boron bonds.
Externí odkaz:
https://doaj.org/article/e8659eb09b804bfb9bf50536728eb2fe