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pro vyhledávání: '"Martin Wehlan"'
Publikováno v:
Journal of Organometallic Chemistry. 613:159-169
The azido complexes [RhCp*(μ-N3)(N3)]2 (Cp*=η-C5Me5), trans-Rh(N3)(CO)(PPh3)2, Na2[Pd(N3)4], Na2[Pd2(μ-N3)2(N3)4] and Na[Au(N3)4], prepared in situ from metal halide precursors and a three- to ten-fold excess of NaN3 in water, react with aliphatic
Autor:
Hans-Heinrich Limbach, Martin Wehlan, ‡ Wolf-Peter Fehlhammer, Rudolf Janoschek, Hans Benedict, and Nicolai S. Golubev
Publikováno v:
Journal of the American Chemical Society. 120:2939-2950
Using a combination of high resolution and dipolar solid state 15N NMR we have determined H/D isotope effects on the nitrogen-hydron (L = H, D) distances and 15N chemical shielding tensors of strongly hydrogen bonded bisisocyanide salts of the type [
Autor:
Martin Wehlan, Hans-Heinrich Limbach, Hans Benedict, Francisco Aguilar-Parrilla, ‡ Wolf-Peter Fehlhammer, Christoph Hoelger, Rudolf Janoschek
Publikováno v:
Journal of Molecular Structure. 378:11-16
In this study, hydrogen/deuterium isotope effects on the geometry and the 15N NMR chemical shifts of strongly hydrogen bonded, solid hydrogen-bisisocyanide salts of the type [MCN⋯L⋯NCM]−X+ 1 (L H, D) are described both experimen