Zobrazeno 1 - 10
of 14
pro vyhledávání: '"Martin Andreas Robert George"'
Publikováno v:
Physical Chemistry Chemical Physics. 25:5529-5549
IRPD spectroscopy of amantadineH+(H2O)n clusters reveal the first microhydration steps of this important pharmaceutical molecular drug and the first spectroscopic impression of its intermolecular interaction with water at the molecular level.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::236c61981aef3726112ba7d36c403dcd
https://doi.org/10.1039/d2cp04556g
https://doi.org/10.1039/d2cp04556g
Publikováno v:
The Journal of Physical Chemistry Letters. 13:449-454
Radical cations of diamondoids, a fundamental class of highly stable cycloalkanes, are intermediates in functionalization reactions and possibly present in the interstellar medium. Herein, we characterize the structure of the radical cation of 1-aman
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7ea1228e9fd9d6048e4adbf734be581f
https://doi.org/10.1021/acs.jpclett.1c03948
https://doi.org/10.1021/acs.jpclett.1c03948
Publikováno v:
Physical Chemistry Chemical Physics. 24:16101-16111
The two isomers of the pharmaceutically active AmaH+ ion identified by IR spectroscopy are the canonical ammonium isomer (I) formed by protonation at the NH2 group and a protonated bicyclic iminium ion (II) formed by ionization of Ama followed by cag
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::beb70e408a9b4223820bdab0c2928ebe
https://doi.org/10.1039/d2cp01947g
https://doi.org/10.1039/d2cp01947g
Publikováno v:
Angewandte Chemie (International Ed. in English)
Diamondoid cations are reactive intermediates in their functionalization reactions in polar solution. Hydration is predicted to strongly activate their C−H bonds in initial proton abstraction reactions. To study the effects of microhydration on the
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::53cd7cb5b4002d21ebe28a3cb44823d5
https://doi.org/10.1002/anie.202003637
https://doi.org/10.1002/anie.202003637
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 28(44)
Radical cations of diamondoids, a fundamental class of very stable cyclic hydrocarbon molecules, play an important role in their functionalization reactions and the chemistry of the interstellar medium. Herein, we characterize the structure, energy,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::a155acde78b0cdbc92af0191bcb9b901
https://pubmed.ncbi.nlm.nih.gov/35611807
https://pubmed.ncbi.nlm.nih.gov/35611807
Publikováno v:
Physical Chemistry Chemical Physics. 22:28123-28139
Hydration of biomolecules and pharmaceutical compounds has a strong impact on their structure, reactivity, and function. Herein, we explore the microhydration structure around the radical cation of the widespread pharmaceutical drug amantadine (C16H1
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f2ace3633c06a7588a99bbc6dd23fc4d
https://doi.org/10.1039/d0cp05299j
https://doi.org/10.1039/d0cp05299j
Publikováno v:
International Journal of Mass Spectrometry. 435:51-60
Although silane-type cations of the form Si x H y + are thought to play a significant role in plasma chemistry and astrochemistry, their structural and energetic properties are largely unexplored in the size range x ≥ 3. Herein, infrared photodisso
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3ccc4540d0f56db97ab3a826ad78e84d
https://doi.org/10.1016/j.ijms.2018.10.005
https://doi.org/10.1016/j.ijms.2018.10.005
Publikováno v:
Angewandte Chemie. 132:12320-12320
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::df2d34b96c9329d02d77a466c20f01a3
https://doi.org/10.1002/ange.202007850
https://doi.org/10.1002/ange.202007850
Publikováno v:
Angewandte Chemie International Edition. 59:12224-12224
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2136118c785ba4159f21fce363772878
https://doi.org/10.1002/anie.202007850
https://doi.org/10.1002/anie.202007850
Publikováno v:
Angewandte Chemie (International ed. in English). 57(11)
We report the spectroscopic characterization of protonated monosilanol (SiH3 OH2+ ) isolated in the gas phase, thus providing the first experimental determination of the structure and bonding of a member of the elusive silanol family. The SiH3 OH2+ i
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::60a2103a1a82fa441f0931b00c30f999
https://pubmed.ncbi.nlm.nih.gov/29341408
https://pubmed.ncbi.nlm.nih.gov/29341408