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pro vyhledávání: '"Marlon Winter"'
Autor:
Marlon Winter, Natallia Peshkur, Mathias A. Ellwanger, Alberto Pérez‐Bitrián, Patrick Voßnacker, Simon Steinhauer, Sebastian Riedel
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany).
A new synthetic access to the Lewis acid [Au(OTeF5)3] and the preparation of the related, unprecedented anion [Au(OTeF5)4]- with inorganic or organic cations starting from commercially available and easy-to-handle gold chlorides are presented. In thi
Autor:
Marlon Winter, Alberto Pérez‐Bitrián, Simon Steinhauer, Niklas Limberg, Mathias A. Ellwanger, Karsten Sonnenberg, Sebastian Riedel
Publikováno v:
Chemistry – A European Journal. 26:16089-16097
Trifluoromethylation of [AuF3 (SIMes)] with the Ruppert-Prakash reagent TMSCF3 in the presence of CsF yields the product series [Au(CF3 )x F3-x (SIMes)] (x=1-3). The degree of trifluoromethylation is solvent dependent and the ratio of the species can