Výsledky vyhledávání

Facile Access to a Stable Divalent Germanium Compound with a Terminal PH2 Group and Related PR2 Derivatives

Autor: Klaus Merz, Matthias Driess, Markus Brym, Shenglai Yao

Publikováno v: Organometallics. 27:3601-3607

The first stable β-diketiminate germanium(II) complexes LGeY [L = CH{(CMe)(2,6-iPr2C6H3N)}2] with terminal phosphanyl groups Y (Y = PH2, PHR, and PR2) are described. Thus, LGePH2 (2) is synthesized...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::0731becb9bb025569e41dedc15b76c1d
https://doi.org/10.1021/om800269f

Zobrazit plný text záznamu

Facile Transformations of a 1,3,5-Triphosphacyclohexadienyl Anion within the Coordination Sphere of Group 13 and 14 Elements: Synthesis of 1,3-Diphosphacyclopentadienyl Complexes and Phosphaorganometallic Cage Compounds

Autor: Cameron Jones, Andreas Stasch, Matthew D. Francis, Markus Brym, Guoxia Jin, David P. Mills

Publikováno v: University of St Andrews CRIS

The reactivity of the lithium triphosphacyclohexadienyl complex Li[1,3,5-MeP3C3But3] toward a range of group 13 and 14 halide complexes has been investigated. The heterocycle reacts with MX (M = Ga, In, or Tl; X = Cl or I) to give the diphosphacyclop

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ece34e1d6897b8d166144b9fb40ef252
https://doi.org/10.1021/om0605581

Zobrazit plný text záznamu

Rare examples of mononuclear, homoleptic antimony(III) and bismuth(III) aryloxides

Autor: Peter C. Junk, Cameron Jones, Markus Brym

Publikováno v: Main Group Chemistry. 5:13-19

Homoleptic [E(Odpp)3] · nL (E = Sb, n = 1, L = C6H12; E = Bi, n = 0; HOdpp = 2,6-diphenylphenol) are conveniently prepared by the treatment of anhydrous ECl3 with LiOdpp in THF. X-ray crystal structures on both compounds show that in the solid state

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::bbfaf90fe22f45718bf36497140302a4
https://doi.org/10.1080/10241220600751384

Zobrazit plný text záznamu

Synthesis and characterisation of a diphosphaalkene, a diphosphaalkyne and the first diphosphavinyl lithium complex

Autor: Cameron Jones, Markus Brym, Florian Brodkorb, Christian Schulten

Publikováno v: Journal of Organometallic Chemistry. 691:1025-1029

The preparation and characterisation of a diphosphaalkene, (Me 3 Si)P C(OSiMe 3 ){C(C 2 H 4 ) 3 C}C(OSiMe 3 ) P(SiMe 3 ), and the second example of a diphosphaalkyne, P C{C(C 2 H 4 ) 3 C}C P, are described. In addition, the reaction of another diphos

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::37c1c1e243cd3d152685d4a28e89b897
https://doi.org/10.1016/j.jorganchem.2005.11.006

Zobrazit plný text záznamu

X-ray structural characterization of some sterically bulky N-donor and N-alkyl Grignard reagents

Autor: Cameron Jones, Philip C. Andrews, Marc Kloth, Peter C. Junk, Markus Brym

Publikováno v: Inorganica Chimica Acta. 359:355-363

[MgBr2(thf)3] (1) and [FisoMg(thf)Cl]2 (2), (Fiso− = [ArNC(H)NAr]−, Ar = C 6 H 3 Pr 2 i - 2 , 6 ), [2-PyC(SiMe3)2Mg(thf)Cl]2 (3), [2-PyC(SiMe3)2Mg(thf)Br]2 (4), and [(2-PyC(SiMe3)2Mg(thf))2(OEt)Cl] · Et2O (5). (2-Py(SiMe3)2CH = 2-{bis-(trimethyl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5f08003dc941a4d9abc3ee98d5d54e4f
https://doi.org/10.1016/j.ica.2005.08.009

Zobrazit plný text záznamu

Auration, Argentation, and Mercuration Reactions of an Iridaphosphirene

Autor: Markus Brym, Cameron Jones, James D. E. T. Wilton-Ely

Publikováno v: Inorganic Chemistry. 44:3275-3282

The reactions of the iridaphosphirene complex [Ir{=C(tBu)P(Cy)}(CO)(PPh3)2] (Cy = cyclohexyl) with either [AuCl(tht)] (tht = tetrahydrothiophene) or AgCl result in the products [Ir{=C(tBu)P[M(Cl)](Cy)}(CO)(PPh3)2], M = Au or Ag. The aurated product c

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::310b4179e79db93298cc473b8d34372b
https://doi.org/10.1021/ic048532u

Zobrazit plný text záznamu

[Untitled]

Autor: Markus Brym, Cameron Jones

Publikováno v: Transition Metal Chemistry. 28:595-599

Two iridium(I) complexes, [IrCl(COD)(PEt3) n ], n = 1 or 2, have been prepared and structurally characterised. Although [IrCl(COD)(PEt3)] is a known compound the spectroscopic data on both compounds is presented and discussed. In addition, the X-ray

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::81f4aa58c06740cb34405179bcc0e243
https://doi.org/10.1023/a:1025044229274

Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání