Výsledky vyhledávání - "Mark Schormann"

Synthesis, Structure, and Luminescent Behavior of Anionic Oligomeric and Polymeric Ag2Au2 Clusters

Autor: Mark Schormann, Nicky Savjani, Luke A. Wilkinson, David L. Hughes, Manfred Bochmann

Publikováno v: Organometallics. 31:7600-7609

Mixtures of silver salts AgX (X = NO3, CF3CO2, CF3SO3) with M[Au(C6F5)2] (M = NBu4, PPh4) gave respectively the ionic mixed-metal clusters [M2{(C6F5)4Au2Ag2X2}]n (1, X = NO3; a, M = NBu4; b, M = PPh4) and [M{(C6F5)4Au2Ag2X}]n, (2a,b, X = CF3CO2; 3a,b

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::26967259f1e8a74bfbc0caf125960f38
https://doi.org/10.1021/om300911h

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Structural variation in gold(I)-chelate systems: Synthesis of an asymmetrically bridged β-diketiminato complex of gold

Autor: Mark Schormann, Nicky Savjani, Manfred Bochmann

Publikováno v: Polyhedron. 38:137-140

The reaction of the potassium diketiminate K[RN C(CF3)CH (CF3)CNR)], where R = 3,5-C6H3Me2, with PPh3AuCl afford the complex [RN C(CF3)CH (CF3)CNR)AuPPh3]. Unlike gold(I) diketiminates without backbone-CF3 substituents, the complex is thermally stabl

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c5de68ec28fbeb6344984bfda2028731
https://doi.org/10.1016/j.poly.2012.02.026

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Synthesis and structures of ferrocenyl-substituted salicylaldiminato complexes of magnesium, titanium and zirconium

Autor: Manfred Bochmann, Mark Schormann, David L. Hughes, Robyn K. J. Bott, Simon J. Lancaster

Publikováno v: Polyhedron. 25:387-396

N -ferrocenyl salicylaldimine (FcPI)H, readily accessible from aminoferrocene and salicylaldehyde, reacts with dibutylmagnesium in THF to afford a red crystalline (FcPI) 2 Mg(THF) 2 ( 2 ). The reactions of the Li(FcPI) with CpTiCl 3 gave CpTiCl 2 (Fc

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::130b8ecd4a9da219758505b94e3b66a5
https://doi.org/10.1016/j.poly.2005.07.012

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Reactivity of Silyl-Substituted Allyl Compounds with Group 4, 5, 9, and 10 Metals: Routes to η3-Allyls, Alkylidenes, and sec-Alkyl Carbocations

Autor: Manfred Bochmann, Shaun Garratt, Mark Schormann

Publikováno v: Organometallics. 24:1718-1724

Whereas the reaction of alkali-metal salts of silyl-allyls E+[C3H3(SiMe3)(2)-1,3](-) (E = Li, K) with group 4 and group 5 metal halides gave intractable reduction products, Co(acac)(3) and Ni(acac)(2) reacted with K[C3H3(SiMe3)(2)-1,3] to give Co{eta

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::87c9ffe6ec6a0c3a541d6969b239346e
https://doi.org/10.1021/om0491692

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Synthesis of cationic zinc complexes from protonated diazadienes and ZnR2 (R=Et, N(SiMe3)2). The crystal structures of [PriDADH][H2N{B(C6F5)3}2], [{PriDADZn(μ-OH)}2][H2N{B(C6F5)3}2]2, and [Ph*DADZnN(SiMe3)2][H2N{B(C6F5)3}2]

Autor: Manfred Bochmann, David L. Hughes, Mark Schormann, Mark D. Hannant

Publikováno v: Inorganica Chimica Acta. 358:1683-1691

Protonation of (MeC=NC6H3Pr2i-2,6)(2) (Pr'DAD) with [H(OEt2)(2)][HN{B(C6F5)(3)}(2)] affords the immonium salt [Pri- DADH][H2N{B(C6F5)(3)}(2)] (1) which shows intra- and inter-ionic NH center dot center dot center dot F hydrogen bonding in the solid s

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d2901c4940a28a35cdfc05faa6fa55fc
https://doi.org/10.1016/j.ica.2004.11.012

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Sterically Hindered Lanthanide Allyl Complexes and Their Use as Single-Component Catalysts for the Polymerization of Methyl Methacrylate and ε-Caprolactone

Autor: David L. Hughes, Mark Schormann, Manfred Bochmann, Timothy J. Woodman

Publikováno v: Organometallics. 23:2972-2979

The reaction of KL3 (L3 = 1,3-C3H3(SiMe3)2) with NdI3(THF)3.5 affords two products, L3NdI2(THF)1.25 and (L3)2NdI(THF)2 (1). The latter has been crystallographically characterized; it has a distorted trigonal-bipyramidal structure with the THF ligands

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::5fc2e587ee7a28ba47dd67e9e12ae0b2
https://doi.org/10.1021/om0499097

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Ansa-metallocenes with BN and BP linkages: the importance of NH⋯FC hydrogen bonding in pentafluorophenyl boron compounds

Autor: Mark Schormann, Manfred Bochmann, Andrew J. Mountford, David L. Hughes, Simon J. Lancaster

Publikováno v: Journal of Organometallic Chemistry. 680:193-205

The reaction of Cp'(CpB)ZrCl2 [CpB=?5-C5H4B(C6F5)2] with LiNHCMe3 gave Cp'(CpB)(µ-NHCMe3)ZrCl, with a constrained-geometry type Cp---B---N chelate ligand. The 19F-NMR spectrum of the zirconium complexes, as well as that of the titanium analogue, rev

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::12ecbc00c41d4d66d531d437c860dacb
https://doi.org/10.1016/s0022-328x(03)00346-2

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