Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Mark S.B. Felix"'
Publikováno v:
Inorganica Chimica Acta Reviews
Inorganica Chimica Acta Reviews, Elsevier, 1993, 213 (1-2), pp.3-10. ⟨10.1016/S0020-1693(00)83807-4⟩
Inorganica Chimica Acta Reviews, 1993, 213 (1-2), pp.3-10. ⟨10.1016/S0020-1693(00)83807-4⟩
Inorganica Chimica Acta Reviews, Elsevier, 1993, 213 (1-2), pp.3-10. ⟨10.1016/S0020-1693(00)83807-4⟩
Inorganica Chimica Acta Reviews, 1993, 213 (1-2), pp.3-10. ⟨10.1016/S0020-1693(00)83807-4⟩
The symmetrical 1,3-diynes, RC2C2R (RMe, Et, Ph, But, SiMe3), react with [Os3(CO)10(MeCN)2] to give the clusters [Os3(μ3,η2-RC2C2R)(μ-CO)(CO)9]. The μ3,η2-coordinated alkyne group does not exchange with the non- coordinated one. As a conseque
Autor:
Kenneth I. Hardcastle, Derek A. Tocher, Mark S.B. Felix, Didier Nuel, Nicholas I. Powell, Antony J. Deeming
Publikováno v:
Journal of Organometallic Chemistry
Journal of Organometallic Chemistry, 1990, 384 (1-2), pp.181-191. ⟨10.1016/0022-328X(90)87065-L⟩
Journal of Organometallic Chemistry, Elsevier, 1990, 384 (1-2), pp.181-191. ⟨10.1016/0022-328X(90)87065-L⟩
Journal of Organometallic Chemistry, 1990, 384 (1-2), pp.181-191. ⟨10.1016/0022-328X(90)87065-L⟩
Journal of Organometallic Chemistry, Elsevier, 1990, 384 (1-2), pp.181-191. ⟨10.1016/0022-328X(90)87065-L⟩
The two related compounds [Os3H(μ,η2-trans-CHCHR)(CO)10] (R = OEt or ferrocenyl C5H4FeC5H5, Fc), have been prepared, the first by insertion of ethyl ethynyl ether (CHCOEt) into [Os3H2(CO)10] and the second by oxidative addition of ethynylferr
Autor:
Mary McPartlin, Trushar Adatia, Harold R. Powell, Ravindra Bhusate, Antony J. Deeming, Shariff E. Kabir, Mark S.B. Felix, Esther B. Boyar
Publikováno v:
J. Chem. Soc., Dalton Trans.. :5-12
The µ3-ethynyl compound [Os3H(CCH)(CO)9] reacts smoothly with ethanol as the solvent to give two isomeric ethanol adducts: [Os3H2(CCHOEt)(CO)9](1) and [Os3H2(CHCOEt)(CO)9](2), derived by ethoxy-group addition at the β- and α-carbon atoms respectiv
Publikováno v:
Polyhedron. 7:1793-1799
The synthesis of [Mo2(η-C5H5)2(CO)4(μ-dppm)] (1) (dppm = Ph2PCH2PPh2) from the parent hexacarbonyl, its spectra, and X-ray structure are reported. The Mo, Mo bond [3.327(1) A] is significantly longer than in known related compounds such as the corr
Publikováno v:
J. Chem. Soc., Chem. Commun.. :461-463
The diyne clusters [Os3(µ3,η2-RCCCCR)(CO)10](R = Me, Et, Ph, But, SiMe3) in hydrocarbon solvent at 120 °C decarbonylate to give the nonacarbonyl clusters [Os3(µ3,η2-C2R)(µ-C2R)(CO)9] when R = Ph, But, or SiMe3, [Os3H(µ3,σ,η2,η2-EtCC–CCCHM