Zobrazeno 1 - 10 of 14 pro vyhledávání: '"Mark D. McClain"'
1
Electronic and structural consequences of n-doping: bithiazole oligomers and partially reduced bithiazolium cations
Autor: Douglas S. Dudis, Mark D. McClain
Publikováno v: Synthetic Metals. 116:199-202
N -methylated-poly(diakyl-bithiazoles), NPABTs, can be reduced to give reasonably stable n-doped polymers. In order to understand the changes in the electronic structure and polymer conformations upon reductive doping of NPABTs, a series of oligomers
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::43f47ad0e2b9979d4ec858d9d68bedbb
https://doi.org/10.1016/s0379-6779(00)00486-0
Zobrazit plný text záznamu
2
Spontaneous polymerization of phenylphosphaethyne
Autor: Mark D. McClain, Todd M. Alam, Gregory M. Jamison, Douglas A. Loy
Publikováno v: Journal of Polymer Science Part A: Polymer Chemistry. 37:129-133
Phosphaalkynes (P'COR) bear striking similarities in bonding and reactivity to terminal alkynes (HC'COR). Longer COP bonds and the lack of pendant organic groups attached to phosphorus make phosphaalkynes potential precursors to conjugated polymers.
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::3dd095223beb963aa68b10067850bae5
https://doi.org/10.1002/(sici)1099-0518(19990115)37:2<129::aid-pola3>3.0.co
Zobrazit plný text záznamu
3
Polymerization of Bis(triethoxysilyl)ethenes. Impact of Substitution Geometry on the Formation of Ethenylene- and Vinylidene-Bridged Polysilsesquioxanes
Autor: Mark D. McClain, Kenneth J. Shea, Douglas A. Loy, Stephen T. Hobson, John Greaves, Joseph P. Carpenter, Stacey A. Yamanaka
Publikováno v: Chemistry of Materials. 10:4129-4140
Preparation of organically-bridged polysilsesquioxanes has been achieved by polymerizing organic monomers with two or more trialkoxysilyl groups per monomer repeat unit. The nature of the organic bridging group has been shown to strongly impact the f
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a9d24d6ec0df46a5d990a8c7d16cbdb4
https://doi.org/10.1021/cm9805424
Zobrazit plný text záznamu
4
A New Poly(3-alkylthiophene) Synthesis via Pd-Catalyzed Coupling of Thienyl Mercuric Chlorides
Autor: Mark D. McClain, M. David Curtis
Publikováno v: Chemistry of Materials. 8:936-944
A new coupling reaction based on the Pd-catalyzed reductive coupling of thienyl mercuric chlorides is described. A variety of substituted thiophenes react with HgCl2 to produce thienyl mercuric chl...
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::893af34c4ed9f58b3b5428114c8da872
https://doi.org/10.1021/cm9505308
Zobrazit plný text záznamu
5
Synthesis of Poly(3-alkylthienylene ketone)s by the Pd-Catalyzed Copolymerization of Carbon Monoxide with Thienyl Mercuric Chlorides
Autor: M. David Curtis, Mark D. McClain
Publikováno v: Chemistry of Materials. 8:945-951
Poly(thienylene ketone)s are formed by the copolymerization of bis(chloromercuri)thiophenes with carbon monoxide. The reaction is carried out in hot pyridine with a Pd catalyst under 500 psi of CO. The polymers, poly(3-methylthienylene ketone), poly(
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::55784cc12efeff7e94174ea67795fa29
https://doi.org/10.1021/cm950590d
Zobrazit plný text záznamu
7
Isolation and Characterization of the Molybdenum Alkylidyne Complex [(F3C)Me2CO]2Mo(C-t-Bu)[N(Ar)PC(H)(CMe2Ph)] and Its Conversion to a Phosphamolybdacyclobutene
Autor: Joseph W. Ziller, David R. Wheeler, Douglas A. Loy, Gregory M. Jamison, Randall S. Saunders, Todd M. Alam, Mark D. McClain
Publikováno v: Organometallics. 15:3244-3246
Novel molybdenum alkylidyne [(F3C)Me2CO]2Mo(C-t-Bu)[N(Ar)PC(H)(CMe2Ph)] (Ar = 2,6-(i-Pr)2C6H3; 3b) is formed in the reaction of tert-butylphosphaalkyne 2 with molybdenum alkylidene 1b. Alkylidyne 3...
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::edf3773b68d173bdfba66ae959f540ca
https://doi.org/10.1021/om960418z
Zobrazit plný text záznamu
8
Cycloaddition of Phosphaalkynes to High-Oxidation-State Metal Alkylidenes: Synthesis and Characterization of a Unique Phosphametallacyclobutene via an Alkoxide Ligand Shift
Autor: Gregory M. Jamison, Randall S. Saunders, David R. Wheeler, Mark D. McClain, Douglas A. Loy, Joseph W. Ziller
Publikováno v: Organometallics. 15:16-18
The phosphametallacycle 3, [ArN][RO]MoC(t-Bu)P(OR)C(H)(t-Bu) (Ar = 2,6-(i-Pr)2-C6H3, R = CMe(CF3)2), is formed from the cycloaddition of tert-butylphosphaacetylene to the high-oxidation-state molybdenum alkylidene [ArN][RO]2MoC(H)(t-Bu), accompanied
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::ebd3eccc8f805e39efd7e0477e4287fc
https://doi.org/10.1021/om950756k
Zobrazit plný text záznamu
9
Controlling Porosity in Bridged Polysilsesquioxanes through Elimination Reactions
Autor: Douglas A. Loy, Sheshasayana Prabakar, Mark D. McClain
Publikováno v: Scopus-Elsevier
The retro Diels-Alder reaction was used to modify porosity in hydrocarbon-bridged polysilsesquioxane gels. Microporous polysilsesquioxanes incorporating a thermally labile Diels-Alder adduct as the hydrocarbon bridging group were prepared by sol-gel
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f6e54c4a69cae9ebd32b21fde9175399
https://doi.org/10.1557/proc-435-277
Zobrazit plný text záznamu

Vyhledávací nástroje:

Upřesnit hledání

Omezení vyhledávání
Plný text Recenzováno Digitální knihovna AV ČR
Zdroje