Zobrazeno 1 - 10
of 64
pro vyhledávání: '"Mario Bakardjiev"'
Autor:
Drahomír Hnyk, Dmytro Bavol, Aleš Růžička, Josef Holub, Mario Bakardjiev, Jan Vrána, Zdeňka Růžičková, Jindřich Fanfrlík, Maksim A. Samsonov
Publikováno v:
Inorganic Chemistry. 60:8428-8431
The electrophilic substitution of icosahedral closo-1-SB11H11 with methyl iodide has resulted in two B-functionalized thiaboranes, 7,12-I2-2,3,4,5,6,8,9,10,11-(CH3)9-1-closo-SB11 and 7,8,12-I3-2,3,4,5,6,9,10,11-(CH3)8-closo-1-SB11, with the former be
Autor:
Jindřich Fanfrlík, Michael L. McKee, Bohumil Štíbr, Zdeňka Růžičková, Drahomír Hnyk, Aleš Růžička, Josef Holub, Mario Bakardjiev
Publikováno v:
Dalton Transactions. 50:12098-12106
Reported herein are mutual rearrangements in the whole series of seven bicapped-square antiprismatic closo-C2B8H10 by means of high-quality computations that disprove the earlier postulated dsd (diamond-square-diamond) scheme for these isomerizations
Autor:
Mario Bakardjiev, Oleg L. Tok, Bohumil Štíbr, Zdeňka Růžičková, Josef Holub, Drahomír Hnyk, Aleš Růžička, Jindřich Fanfrlík
Publikováno v:
Inorganic Chemistry. 58:2865-2871
Methyl-camouflaged dicarbaboranes closo-1,2- and 1,10-H2C2B8Me8 have been prepared in high yields either from nido-5,6-H2C2B8H10 or closo-1,2-H2C2B8H8 via electrophilic methylation reactions and cl...
Publikováno v:
Inorganica Chimica Acta. 538:121000
Autor:
Mario, Bakardjiev, Josef, Holub, Dmytro, Bavol, Jan, Vrána, Maksim A, Samsonov, Aleš, Růžička, Zdeňka, Růžičková, Jindřich, Fanfrlík, Drahomír, Hnyk
Publikováno v:
Inorganic chemistry. 60(12)
The electrophilic substitution of icosahedral
Autor:
Mario, Bakardjiev, Josef, Holub, Zdeňka, Růžičková, Aleš, Růžička, Jindřich, Fanfrlík, Bohumil, Štíbr, Michael L, McKee, Drahomír, Hnyk
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 50(35)
Reported herein are mutual rearrangements in the whole series of seven bicapped-square antiprismatic
Publikováno v:
Molecules
Molecules, Vol 25, Iss 4, p 814 (2020)
Molecules, Vol 25, Iss 4, p 814 (2020)
Ring cleavage of cyclic ether substituents attached to a boron cage via an oxonium oxygen atom are amongst the most versatile methods for conjoining boron closo-cages with organic functional groups. Here we focus on much less tackled chemistry of the
Publikováno v:
Inorganic Chemistry. 57:1368-1372
Alkylation of the [nido-5,6-R12C2B8H9]− anions (where R1 = H and Me) with alkyl halides (RX, where R = primary and secondary alkyls) in boiling tetrahydrofuran (THF) proceeds via unusual H2 elimination, followed by cage closure to give a series of
Autor:
Drahomír Hnyk, Mario Bakardjiev, Aleš Růžička, Bohumil Štíbr, Jindřich Fanfrlík, Josef Holub, Zdeňka Růžičková, Oleg L. Tok, Zbyněk Špalt
Publikováno v:
Dalton Transactions. 47:11070-11076
Reported are procedures leading to the first types of methyl camouflaged dicarbadecaboranes with fewer than eleven vertices. The compounds contain the closo-1,6-C2B8 scaffolding inside the egg-shaped hepta – decamethyl sheath, which imparts unusual
Publikováno v:
Inorganic Chemistry. 56:5971-5975
Initial studies on electrophilic halogenation of the dicarbaborane closo-1,2-C2B8H10 (1) have been carried out to reveal that the substitution takes place at B7 and B10 vertexes, which are the most removed from the CH positions. The course of the hal