Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Mario, Janjetovic"'
Publikováno v:
Organic Letters. 18:2804-2807
A facile iodination protocol of unactivated alkyl fluorides using catalytic amounts of YbI3(THF)3 in the presence of iodotrimethylsilane as a stoichiometric fluoride trapping agent is presented. (1)H NMR spectroscopy demonstrates a two-step catalytic
Publikováno v:
Angewandte Chemie International Edition. 52:12073-12076
Publikováno v:
ChemInform. 47
Publikováno v:
Chemical communications (Cambridge, England). 51(68)
A mild and distinct methodology for instantaneous β-amino fluoride substitution mediated by La[N(SiMe3)2]3 has been developed. The reaction proceeds via a reactive aziridinium ion intermediate, which readily reacts with various nucleophiles. This al
Publikováno v:
ChemInform. 46
A new method for C—F bond activation and direct transformation into a C—N bond is reported.
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 21(9)
A procedure for chemoselectively manipulating the strong aliphatic C-F bond with direct transformation into a C-N bond under mild conditions is reported. The activation and subsequent substitution of primary alkyl fluorides is mediated by La[N(SiMe3)
Publikováno v:
ChemInform. 45
Publikováno v:
Angewandte Chemie (International ed. in English). 52(46)
Publikováno v:
ChemInform. 44
Primary, secondary, and tertiary alkyl fluorides (I) can be efficiently reduced using stoichiometric amounts of Sm(HMDS)2 in hexane.
Publikováno v:
Synfacts. 11:0537-0537