Zobrazeno 1 - 10
of 54
pro vyhledávání: '"Marilín Vivanco"'
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 49(20)
New trinuclear gold(i) N-arylimidazolate cluster complexes have been synthesized from cationic [Au(CNR)2]+ isocyanide complexes and their structure and photoluminescence behavior have been compared with those of their 1-methylimidazolate counterpart.
Publikováno v:
Organometallics. 36:1035-1041
DFT theoretical calculations for the base-induced transmetalation process of protic N-heterocyclic carbenes of imidazol-2-ylidene type from Mn(I) to Au(I) have been carried out. The reaction mechanism found involves the formation of key reaction inte
Autor:
Javier Ruiz, María A. Mateo, Juan F. Van der Maelen, Daniel Sol, Marilín Vivanco, Lucía García
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
instname
A subtle change in the substituents at the nitrogen atoms in the N,N′-diarylformamidine complexes of formula fac-[Mn(RN═C(H)NHR)(bipy)(CO)3]+ (1a, R = phenyl; 1b, R = 4-dimethylaminophenyl) produces, upon deprotonation, either the monodentate for
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bd90cc5bb3b1fcb8b0ab29ee1486be8d
http://hdl.handle.net/10261/210828
http://hdl.handle.net/10261/210828
Publikováno v:
Angewandte Chemie. 128:8526-8530
A new protocol for the synthesis of protic bis(N-heterocyclic carbene) complexes of Au(I) by a stepwise metal-controlled coupling of isocyanide and propargylamine is described. They are used as tectons for the construction of supramolecular architect
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 47(18)
The isocyanide ligands in complexes fac-[Mn(CNR)(bipy)(CO)3]+ are selectively transformed into formamidines, carbodiimides and formimidates upon nucleophilic addition of NH2Me or alkoxides and subsequent treatment with Ag2O, which promotes tautomeriz
Publikováno v:
Scopus
RUO. Repositorio Institucional de la Universidad de Oviedo
instname
RUO. Repositorio Institucional de la Universidad de Oviedo
instname
The isocyanide ligands in complexes fac-[Mn(CNR)(bipy)(CO)3]+ are selectively transformed into formamidines, carbodiimides and formimidates upon nucleophilic addition of NH2Me or alkoxides and subsequent treatment with Ag2O, which promotes tautomeriz
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8a4c1670e30013c029a723327ea2411c
http://hdl.handle.net/10651/48919
http://hdl.handle.net/10651/48919
Publikováno v:
Angewandte Chemie International Edition. 54:4212-4216
By means of a combined experimental and theoretical approach, the electronic features and chemical behavior of metalla-N-heterocyclic carbenes (MNHCs, N-heterocyclic carbenes containing a metal atom within the heterocyclic skeleton) have been establi
Publikováno v:
Digital.CSIC. Repositorio Institucional del CSIC
instname
instname
A variety of half-sandwich iron(II) complexes with diprotic acyclic diaminocarbene ligands (pADCs) have been obtained by reaction of the cationic complexes [Fe(Cp)(CO)2(CNR)]+ and [Fe(Cp)(CO)(CNR)2]+ with methylamine, and their acid–base behaviour
Publikováno v:
Organometallics. 31:6420-6427
The reactivity of the mixed-ligand carbonyl–isocyanide complexes fac-[Mn(CNR)(CO)3(bipy)]+ (1a, R = Ph; 1b, R = xylyl; 1c, R = Me; 1d, R = CH2Ph; 1e, R = tBu) with the primary amines NH2Me and NH2CH2CH2CH2Br has been studied. Nucleophilic addition
Publikováno v:
Chem. Commun.. 50:5597-5599
A variety of λ5-phosphole derivatives bearing up to three distinct peripheral functionalities have been prepared by regiospecific [3+2] cycloaddition reactions of the diphosphinoketenimine (PPh2)2CCNtBu (1) with electron-poor alkenes. Selective deri