Zobrazeno 1 - 10
of 59
pro vyhledávání: '"Marie-Paule Simonnin"'
Publikováno v:
ChemInform. 21
1 H and 13C n.m.r. data are reported for a series of ortho and para nitro-substituted diphenylmethanes and related diphenylmethyl anions. In the case of the neutral molecules, a predominance of the skew conformation is suggested for mono- and di-o ni
Publikováno v:
The Journal of Organic Chemistry. 43:855-859
Autor:
Jacqueline Seyden-Penne, Eli Breuer, Marie-José Pouet, Marie-Paule Simonnin, Tekla Bottin-Strzalko
Publikováno v:
J. Chem. Soc., Perkin Trans. 2. :1801-1805
A structural and conformational study of the electron-withdrawing substituted phosphonates 2-oxo-1,3,2-dioxaphosphorinanes (1) and (2) and of the related anionic species (3, K+) and (4, K+) in dimethyl sulphoxide has been made. Phosphonates (1) and (
Publikováno v:
Canadian Journal of Chemistry. 60:1988-1995
Reaction of 1,3,5-trinitrobenzene (TNB) with pyrrole, 2,5-dimethyl pyrrole, and 2,4-dimethyl-3-ethyl pyrrole in the presence of a strong base (CH3O−) yields nitrogen- and/or carbon-bonded 1:1 σ-complexes in dimethylsulphoxide (DMSO). Depending on
Publikováno v:
Canadian Journal of Chemistry. 58:65-71
The reaction of methoxide ion with 2-nitro-4-trifluoromethylsulfonylanisole, 4-nitro-2-triftuoromethylsulfonylanisole and 2,4- bis(trifluoromethylsulfonyl)anisole in DMSO has been studied by 1H and 19F nmr. Evidence for the transient formation of gem
Autor:
Odile Convert, Christian Bellec, Guy Quéguiner, Marie-Paule Simonnin, Nelly Plé, Joseph Armand, Line Boulares
Publikováno v:
Canadian Journal of Chemistry. 63:3210-3215
A conformational study of 1,4-diacetyl-1,4-dihydro-6,7-dimethylquinoxaline is carried out by low temperature nmr in CD2Cl2. Important acetyl rotation induced shifts have been observed for the peri and ortho protons. These results, together with low t
Autor:
Marie-Paule Simonnin, Michele Philoche-Levisalles, Joseph Armand, Claudette Bois, Marie-José Pouet
Publikováno v:
Canadian Journal of Chemistry. 60:349-354
It is shown by X-ray crystallography that the 1,4-dihydropyrazine skeleton of 1,4-diacetyl-1,4-dihydro-2,3-diphenylpyrazine 2 has a boat shape. The C(2)–C(3) and C(5)–C(6) double bonds are localized; therefore 2 does not exist as an azahomoaromat
Publikováno v:
Journal of Fluorine Chemistry. 36:439-448
Fluorine and proton chemical shifts for various trifluoromethylsulfonyl thiophene, selenophene, furan and N-methylpyrrole derivatives are reported and compared with those for nitro analogs. The 19F chemical shift of the SO2CF3group is found to be ins
Autor:
Tekla Bottin-Strzalko, Jacques Corset, Francoise Froment, Marie Jose Pouet, Jacqueline Seyden-Penne, Marie Paule Simonnin
Publikováno v:
The Journal of Organic Chemistry. 45:1270-1276
Publikováno v:
Tetrahedron Letters. 23:4079-4082
The reaction of 1,3,5-trinitrobenzene (TNB) with imidazolide ion (Im-) provides the first example of the ambifunctional nucleophilic reactivity of this anion towards an aromatic electrophile. The N-adduct 1 is formed under kinetic control but the C-a