Electrochemical Properties of a Rhodium(III) Mono-Terpyridyl Complex and Use as a Catalyst for Light-Driven Hydrogen Evolution in Water

Autor: Fakourou Camara, Thomas Gavaggio, Baptiste Dautreppe, Jérôme Chauvin, Jacques Pécaut, Dmitry Aldakov, Marie-Noëlle Collomb, Jérôme Fortage

Publikováno v: Molecules, Vol 27, Iss 19, p 6614 (2022)

Molecular hydrogen (H2) is considered one of the most promising fuels to decarbonize the industrial and transportation sectors, and its photocatalytic production from molecular catalysts is a research field that is still abounding. The search for new

Externí odkaz: https://doaj.org/article/7933607a3c00444c8932eff9ea786584

Propriétés électrochimiques d'un complexe mono-terpyridyle de Rhodium(III) et utilisation comme catalyseur pour le dégagement photo-induit d'hydrogène dans l'eau

Autor: Fakourou Camara, Thomas Gavaggio, Baptiste Dautreppe, Jérôme Chauvin, Jacques Pécaut, Dmitry Aldakov, Marie-Noëlle Collomb, Jérôme Fortage

Publikováno v: Molecules; Volume 27; Issue 19; Pages: 6614
Molecules
Molecules, 2022, 27 (19), pp.6614. ⟨10.3390/molecules27196614⟩

Molecular hydrogen (H2) is considered one of the most promising fuels to decarbonize the industrial and transportation sectors, and its photocatalytic production from molecular catalysts is a research field that is still abounding. The search for new

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2b9e45e3ec9e526d891e831081538f57

Self-Assembled Heterometallic Complexes by Incorporation of Calcium or Strontium Ion into a Manganese(II) 12-Metallacrown-3 Framework Supported by a Tripodal Ligand with Pyridine-Carboxylate Motifs: Stability in Their Manganese(III) Oxidized Form

Autor: Jacques Pécaut, Jérôme Fortage, Eric Gouré, Marie-Noëlle Collomb, Florian Molton, Catalina N. Astudillo, Bertrand Gerey, Selim Sirach

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, American Chemical Society, 2021, 60 (11), pp.7922-7936. ⟨10.1021/acs.inorgchem.1c00457⟩
Inorganic Chemistry, 2021, 60 (11), pp.7922-7936. ⟨10.1021/acs.inorgchem.1c00457⟩

International audience; We report on the isolation of a new family of μ-carboxylato-bridged metallocrown (MC) compounds by self-assembly of the recently isolated hexadentate tris(2-pyridylmethyl)amine ligand tpada2- incorporating two carboxylate uni

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fe61c4fafa20ccaf194aae90071808f2
https://doi.org/10.1021/acs.inorgchem.1c00457

Electrophotocatalysis: Cyclic Voltammetry as an Analytical Tool

Autor: Jérôme Fortage, Cyrille Costentin, Marie-Noëlle Collomb

Publikováno v: Journal of Physical Chemistry Letters
Journal of Physical Chemistry Letters, American Chemical Society, 2020, 11 (15), pp.6097-6104. ⟨10.1021/acs.jpclett.0c01662⟩

International audience; Electrophotocatalysis (e-PC) is currently experiencing a renewed interest. By taking advantage of the highly oxidizing or reducing power of excited state of electrogenerated ion radicals, it allows thermodynamically difficult

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::34b0b06b02d1bac043fc1c9b304c818f
https://doi.org/10.1021/acs.jpclett.0c01662

Catalytic light-triggered reduction promoted by a dithienylethene derivative

Autor: Amina Khettabi, Nicolas Leconte, Saioa Cobo, Frédéric Lafolet, Arkadiusz Grempka, Marie-Noëlle Collomb, Damien Jouvenot, Elarbi Chatir

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2020, 26 (59), pp.13359-13362. ⟨10.1002/chem.201905825⟩

International audience; A pyridinium substituted dithienylethene derivative was used for the first time as an efficient photo-reducing agent of two different substrates. This reaction exhibits high catalytic yields due to the continuous regeneration

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dcf349bbc7abad82d903cead7f7884a5
https://hal.archives-ouvertes.fr/hal-03064875/file/Manuscript_HAL.pdf