Zobrazeno 1 - 10
of 55
pro vyhledávání: '"Marie-France Llauro"'
Publikováno v:
European Polymer Journal. 43:1549-1556
Microstructural studies of Poly(vinyl alcohol-co-vinyl acetate)-g-polycaprolactone (PVA-Ac)-g-(PCL) were realized principally using NMR. Initial PVA-Ac has a rather blocky structure with an average sequence length of PVA units equal to 12.5. During t
Autor:
A. Michel, Marie-France Llauro
Publikováno v:
Comptes Rendus Chimie. 9:1363-1369
Interchange reactions involving esters were used in reactive processing with a view to obtaining polymer blends with stabilized morphology. Dibutyltinoxide (DBTO) appeared to be an excellent catalyst for these reactions. In fact, it was shown that th
Autor:
Véronique Bounor-Legaré, Alain Michel, Christiane Monnet, Marie-France Llauro, J. Lacoste, Philippe Cassagnau
Publikováno v:
Journal of Polymer Science Part A: Polymer Chemistry. 43:2207-2223
This article deals with a new way of improving the melt viscosity of linear poly(ethylene terephthalate) (PET) chains through the reaction of the PET end groups (alcohol and acid) with new chain extenders, 3-(triethoxysilyl)propylsuccinic anhydride (
Publikováno v:
Polymer International. 53:484-494
It was shown that the crosslinking of ethylene-co-vinyl acetate (EVA) copolymer by a tetraalkoxysilane in molten state, in the temperature range 100–250 °C, was obtained only in the presence of dibutyltin oxide. At this temperature EVA pendant est
Autor:
Laurent Veron, Christian Pichot, Franck D'Agosto, Marie-Thérèse Charreyre, Marie-France Llauro
Publikováno v:
Macromolecular Chemistry and Physics. 202:1689-1699
The kinetics of free radical solution (co)polymerization of N-acryloylmorpholine (NAM) and N-acryloxysuccinimide (NAS) have been investigated at 60°C in 1,4-dioxane using 2,2'-azoisobutyronitrile as the initiator. First, the k p /k 1/2 t value for t
Publikováno v:
Macromolecular Chemistry and Physics. 201:12-20
In order to outline the placement of the monomer units during the heterogeneous anionic coordinated polymerization of propylene oxide, the regioselectivity of the first monomer insertion at the initiator was examined by 1 H NMR. To start, aluminium b
Publikováno v:
Macromolecules. 32:6938-6943
Styrenic block-copolymer polymerizable surfactants, when engaged in emulsion polymer- ization of core-shell acrylic latexes, are forming copolymers containing a large majority of monomer units. These copolymers can be extracted, and analyzed, after e
Publikováno v:
Journal of Organometallic Chemistry. 575:286-300
The product of the reaction of primary and secondary amides with dibutyltin oxide is shown to be a dimeric 1,3-diacyloxytetrabutyldistannoxane. The reaction was studied in bulk with model amides at 180°C, avoiding perfect anhydrous conditions, in vi
Publikováno v:
Journal of Organometallic Chemistry. 558:19-33
A set of 1-D and 2-D, 13 C- and 119 Sn-NMR experiments—both in solution and in the solid state—exhibit a common peculiarity of the monofunctional tetrabutyldistannoxanes of general formulae R 4 Sn 2 X 2 O in comparison with the no problematic NMR