Zobrazeno 1 - 10 of 20 pro vyhledávání: '"Marie Fustier‐Boutignon"'
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Double α,α CH bond insertion into sp3 CH2 moiety: synthesis of a Fe carbene bis-hydride dinitrogen complex
Autor: Nathalie Saffon-Merceron, Marie Fustier-Boutignon, Anthony Cavaillé, Nicolas Mézailles, Julien Petit
Publikováno v: Dalton Transactions
Dalton Transactions, Royal Society of Chemistry, 2021, 50 (27), pp.9554-9559. ⟨10.1039/D1DT00610J⟩
Dalton Transactions, 2021, 50 (27), pp.9554-9559. ⟨10.1039/D1DT00610J⟩
Reduction of high spin paramagnetic complex [(κ2-P, P′-PCH2PCy)FeCl2] 2 by two electrons under N2 resulted in the formation of two isomeric low spin diamagnetic complexes 3trans and 3cis [Fe(κ3-P,C,P′-PCPCy)(H)2(N2)]. Cristallization allowed is
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3e382a2c3e31a400e889f1b83f842c25
https://doi.org/10.1039/d1dt00610j
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4
Double α,α CH bond insertion into sp
Autor: Julien, Petit, Anthony, Cavaillé, Nathalie, Saffon-Merceron, Marie, Fustier-Boutignon, Nicolas, Mézailles
Publikováno v: Dalton transactions (Cambridge, England : 2003). 50(27)
Reduction of high spin paramagnetic complex [(κ2-P, P'-PCH2PCy)FeCl2] 2 by two electrons under N2 resulted in the formation of two isomeric low spin diamagnetic complexes 3trans and 3cis [Fe(κ3-P,C,P'-PCPCy)(H)2(N2)]. Cristallization allowed isolat
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::e73720fe2b59a54a18b539525125ae11
https://pubmed.ncbi.nlm.nih.gov/34159989
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6
Catalytic Reduction of N 2 to Borylamine at a Molybdenum Complex
Autor: Soukaina Bennaamane, Andrea Mulas, Théo Personeni, Maria F. Espada, Nathalie Saffon-Merceron, Marie Fustier-Boutignon, Nicolas Mézailles, Christophe Bucher
Publikováno v: Angewandte Chemie International Edition
Angewandte Chemie International Edition, 2021, 60 (37), pp.20210-20214. ⟨10.1002/anie.202106025⟩
Angewandte Chemie International Edition, Wiley-VCH Verlag, 2021, 60 (37), pp.20210-20214. ⟨10.1002/anie.202106025⟩
International audience; Catalytic formation of borylamines from atmospheric N2 is achieved for the first time using a series of homogenous (triphosphine)Mo complexes. Stepwise functionnalization of the (triphosphine)Mo-nitrido complex with chlorobora
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::02ce39d2df75a30f1e0d5b3f9cf28a5b
https://hal.science/hal-03758782/document
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7
Stepwise Functionalization of N 2 at Mo: Nitrido to Imido to Amido - Factors Favoring Amine Elimination from the Amido Complex
Autor: Maria F. Espada, Noel Nebra, Eric Clot, Ikram Yagoub, Soukaina Bennaamane, Nathalie Saffon-Merceron, Marie Fustier-Boutignon, Nicolas Mézailles
Publikováno v: European Journal of Inorganic Chemistry
European Journal of Inorganic Chemistry, 2020, 2020 (15-16), pp.1499-1505. ⟨10.1002/ejic.201901295⟩
European Journal of Inorganic Chemistry, Wiley-VCH Verlag, 2020, 2020 (15-16), pp.1499-1505. ⟨10.1002/ejic.201901295⟩
International audience; Functionalization of nitrido complex [(P Ph P2 Cy)Mo(N)(I)] by a bis-silane in concentrated medium generates the hydrido-imido complex [(P Ph P2 Cy)Mo(H)(=NSiMe2CH2CH2SiMe2H)(I)]. Abstraction of the iodide by thallium salt TlX
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::000a2929827006d2ee187687b51e0601
https://hal.science/hal-03012876
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8
[(dcpp)Ni( η 2 -Arene)] Precursors: Synthesis, Reactivity, and Catalytic Application to the Suzuki–Miyaura Reaction
Autor: Emmanuel Nicolas, Olivier Thillaye Du Boullay, Alexia Ohleier, Elixabete Rezabal, Florian D'Accriscio, Gilles Frison, Marie Fustier-Boutignon, Nicolas Mézailles, Nathalie Saffon-Merceron, Matthieu Demange, Noel Nebra
Publikováno v: Organometallics
Organometallics, American Chemical Society, 2020, 39 (10), pp.1688-1699. ⟨10.1021/acs.organomet.9b00834⟩
Organometallics, 2020, 39 (10), pp.1688-1699. ⟨10.1021/acs.organomet.9b00834⟩
International audience; The complexes (Cy2PC3H6PCy2)Ni(η2-arene) (arene = toluene (3), naphthalene (4)) have been synthesized and studied in detail. Displacement reactions of the toluene ligand afford the complexes (Cy2PC3H6PCy2)Ni(η2-styrene) (5),
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e6d78252d79b24d48b741faffa4adc06
https://hal.archives-ouvertes.fr/hal-02911077/file/postprint.pdf
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9
Synthesis and Reactivity of an End-Deck cyclo -P4 Iron Complex
Autor: Marie Fustier-Boutignon, Nicolas Mézailles, Nathalie Saffon-Merceron, Anthony Cavaillé, Noel Nebra
Publikováno v: Angewandte Chemie. 130:1892-1896
Reduction of the FeII complex [(Ph PP2Cy )FeCl2 ] (2) generated an electron-rich and unsaturated Fe0 species, which was reacted with white phosphorus. The resulting new complex, [(Ph PP2Cy )Fe(η4 -P4 )] (3), is the first iron cyclo-P4 complex and th
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a2a9d189b2d467f302e993c21addf79d
https://doi.org/10.1002/ange.201711130
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10
C−H Bond Trifluoromethylation of Arenes Enabled by a Robust, High-Valent Nickel(IV) Complex
Autor: Nathalie Saffon-Merceron, Noel Nebra, Marie Fustier-Boutignon, Nicolas Mézailles, Florian D'Accriscio, Pilar Borja
Publikováno v: Angewandte Chemie International Edition. 56:12898-12902
The robust, high-valent NiIV complex [(Py)2NiIVF2(CF3)2] (Py=pyridine) was synthesized and fully characterized by NMR spectroscopy, X-ray diffraction, and elemental analysis. It reacts with aromatic compounds at 25 °C to form the corresponding benzo
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::395de2a0478fadf4aa8c511c1eab331a
https://doi.org/10.1002/anie.201706237
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