Effect of the microstructure of n-butyl acrylate/N-isopropylacrylamide copolymers on their thermo-responsiveness, self-organization and gel properties in water

Autor: Stéphane Gineste, Fang Yin, Mariana Beija, Juliette S. Behra, Nancy Lauth-de Viguerie, Bruno Payré, Annie Brûlet, Juliette Fitremann, Mathias Destarac, Jean-Daniel Marty

Publikováno v: Journal of Colloid and Interface Science
Journal of Colloid and Interface Science, 2020, 578, pp.685-697. ⟨10.1016/j.jcis.2020.06.005⟩
Journal of Colloid and Interface Science, Elsevier, 2020, 578, pp.685-697. ⟨10.1016/j.jcis.2020.06.005⟩

International audience; AbstractHypothesisPolymer composition, microstructure, molar mass, architecture… critically affect the properties of thermoresponsive polymers in aqueous media.ExperimentsThe behaviour of n-isopropylacrylamide and n-butyl ac

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::08a9b319c81926ca1e280c33f1be927e
https://doi.org/10.1016/j.jcis.2020.06.005

Advantages of Block Copolymer Synthesis by RAFT-Controlled Dispersion Polymerization in Supercritical Carbon Dioxide

Autor: Mariana Beija, Stephen Rimmer, James Jennings, Helen Willcock, Rachel K. O'Reilly, Jeremy T. Kennon, Steven M. Howdle

Publikováno v: Macromolecules. 46:6843-6851

Reversible addition–fragmentation chain transfer (RAFT)-controlled block copolymer synthesis using dispersion polymerization in supercritical carbon dioxide (scCO2) shows unprecedented control over blocking efficiency. For PMMA-b-PBzMA and PMMA-b-P

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::637fc4d932ccdb05f3c089efa49dbe34
https://doi.org/10.1021/ma401051e

One-Pot Synthesis of Block Copolymers in Supercritical Carbon Dioxide: A Simple Versatile Route to Nanostructured Microparticles

Autor: Paul E. Mignot, Mariana Beija, James Jennings, Alexandre P. Richez, Samuel D. Cooper, Kristofer J. Thurecht, Steven M. Howdle, Kevin S. Jack

Publikováno v: Journal of the American Chemical Society. 134:4772-4781

We present a one-pot synthesis for well-defined nanostructured polymeric microparticles formed from block copolymers that could easily be adapted to commercial scale. We have utilized reversible addition-fragmentation chain transfer (RAFT) polymeriza

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0005ab7f37a62133541754b52c420a27
https://doi.org/10.1021/ja210577h

RAFT/MADIX polymers for the preparation of polymer/inorganic nanohybrids

Autor: Jean-Daniel Marty, Mariana Beija, Mathias Destarac

Publikováno v: Progress in Polymer Science. 36:845-886

Organic–inorganic hybrid nanocomposites are an emerging class of materials that hold significant promise due to their outstanding properties, which usually arise from a combined and/or synergistic effect of the properties of their organic and inorg

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a47207ac5342cf8f5c22512637d1d0e5
https://doi.org/10.1016/j.progpolymsci.2011.01.002

RAFT polymerization and self-assembly of thermoresponsive poly(N-decylacrylamide-b-N,N-diethylacrylamide) block copolymers bearing a phenanthrene fluorescent α-end group

Autor: José M. G. Martinho, Telmo J. V. Prazeres, Mariana Beija, Marie-Thérèse Charreyre, José Paulo S. Farinha

Publikováno v: Polymer. 51:355-367

Phenanthrene α-end-labeled poly( N -decylacrylamide- b - N , N -diethylacrylamide) (PDcA n - b -PDEA m ) block copolymers consisting in a highly hydrophobic block ( n = 11) and a thermoresponsive block with variable length (79 ≤ m ≤ 468) were sy

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f012f16cac8f4572158eec18ee18d818
https://doi.org/10.1016/j.polymer.2009.11.055