Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Marian Rauser"'
Publikováno v:
Early Main Group Metal Catalysis
Publikováno v:
Angewandte Chemie International Edition. 58:6713-6717
A rare reductive coupling of nitro compounds with organohalides has been realized. The reaction is initiated by a partial reduction of the nitro group to a nitrenoid intermediate. Therefore, not only aromatic but also aliphatic nitro compounds are ef
Publikováno v:
Angewandte Chemie. 130:6005-6009
In analogy to the classical reaction of C-B bonds with peroxides, the first oxidative functionalization of aminoboranes through a 1,2-N migration was realized. Readily available aliphatic nitro compounds are thereby transformed into N- and O-function
Publikováno v:
Chemistry - A European Journal. 24:3970-3974
The first general protocol for the direct reductive N-functionalization of aliphatic nitro compounds is presented. The nitro group is partially reduced to a nitrenoid, with a mild and readily available combination of B2 pin2 and zinc organyls. Thereb
Publikováno v:
Angewandte Chemie International Edition. 56:11570-11574
An exceptionally general electrophilic amination, which directly transforms commercially available nitroarenes into alkylated aromatic aminoboranes with zinc organyl compounds was developed. The reaction starts with a two-step partial reduction of th
Publikováno v:
Angewandte Chemie (International ed. in English). 57(20)
In analogy to the classical reaction of C-B bonds with peroxides, the first oxidative functionalization of aminoboranes through a 1,2-N migration was realized. Readily available aliphatic nitro compounds are thereby transformed into N- and O-function
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 21(45)
The first transition metal-free cycloisomerization of easily accessible diynols is presented as a novel approach to bicyclic 2H-pyrans. As a one-step protocol, the reaction proceeds in a single reaction cascade by intertwining mechanistic fragments b