Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Marian, Rauser"'
Publikováno v:
Early Main Group Metal Catalysis
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::df6d73faa9e350349fb5109a22bc369b
https://doi.org/10.1002/9783527818020.ch11
https://doi.org/10.1002/9783527818020.ch11
Publikováno v:
Angewandte Chemie International Edition. 58:6713-6717
A rare reductive coupling of nitro compounds with organohalides has been realized. The reaction is initiated by a partial reduction of the nitro group to a nitrenoid intermediate. Therefore, not only aromatic but also aliphatic nitro compounds are ef
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::dd64939aa6698ef1470a40df4f7d31c5
https://doi.org/10.1002/anie.201814197
https://doi.org/10.1002/anie.201814197
Publikováno v:
Angewandte Chemie. 130:6005-6009
In analogy to the classical reaction of C-B bonds with peroxides, the first oxidative functionalization of aminoboranes through a 1,2-N migration was realized. Readily available aliphatic nitro compounds are thereby transformed into N- and O-function
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::002de40b56ad91c522a164f27cc2b13b
https://doi.org/10.1002/ange.201803168
https://doi.org/10.1002/ange.201803168
Publikováno v:
Chemistry - A European Journal. 24:3970-3974
The first general protocol for the direct reductive N-functionalization of aliphatic nitro compounds is presented. The nitro group is partially reduced to a nitrenoid, with a mild and readily available combination of B2 pin2 and zinc organyls. Thereb
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3d0e07cec46123774227977dc503e09c
https://doi.org/10.1002/chem.201705986
https://doi.org/10.1002/chem.201705986
Publikováno v:
Angewandte Chemie International Edition. 56:11570-11574
An exceptionally general electrophilic amination, which directly transforms commercially available nitroarenes into alkylated aromatic aminoboranes with zinc organyl compounds was developed. The reaction starts with a two-step partial reduction of th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::101df2124c216ba2b4bf34a322d89d24
https://doi.org/10.1002/anie.201705356
https://doi.org/10.1002/anie.201705356
Publikováno v:
Angewandte Chemie (International ed. in English). 57(20)
In analogy to the classical reaction of C-B bonds with peroxides, the first oxidative functionalization of aminoboranes through a 1,2-N migration was realized. Readily available aliphatic nitro compounds are thereby transformed into N- and O-function
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::084c4f38333feedc6979bb21fb7bf154
https://pubmed.ncbi.nlm.nih.gov/29630762
https://pubmed.ncbi.nlm.nih.gov/29630762
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 21(45)
The first transition metal-free cycloisomerization of easily accessible diynols is presented as a novel approach to bicyclic 2H-pyrans. As a one-step protocol, the reaction proceeds in a single reaction cascade by intertwining mechanistic fragments b
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ec676c7eeb78d2ab16aaa544929b7981
https://pubmed.ncbi.nlm.nih.gov/26403228
https://pubmed.ncbi.nlm.nih.gov/26403228