Zobrazeno 1 - 10
of 30
pro vyhledávání: '"Maria T. Lockhart"'
A mild and mass-efficient procedure based on the one-pot diazotization-azidodediazoniation of aromatic amines is described. A wide range of aryl azides are obtained in moderate to high yields by using tributyltin azide as an effective and reusable az
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bd5f34ae181f52590d82bd7acabfd35b
https://www.sciencedirect.com/science/article/pii/S0022328X16305502#!
https://www.sciencedirect.com/science/article/pii/S0022328X16305502#!
Publikováno v:
ARKIVOC, Vol 2011, Iss 7, Pp 210-220 (2011)
The synthesis in good yields (71-85%) of di- and tristannylated benzenes from commercially available anilines, involving their conversion to the corresponding aryltrimethylammonium salts followed by the reaction with Me3SnNa 1 in liquid ammonia, is d
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::161b1a2f05037b71320b2aa0f321e933
https://www.arkat-usa.org/arkivoc-journal/browse-arkivoc/ark.5550190.0012.718
https://www.arkat-usa.org/arkivoc-journal/browse-arkivoc/ark.5550190.0012.718
Publikováno v:
Journal of Organometallic Chemistry. 695:2578-2585
A selective two-step synthesis of either mono- or distannylated pyridines from commercially available pyridinols, involving its conversion to the corresponding diethyl pyridyl phosphates (pyDEP) followed by the reaction with Me3SnNa in liquid ammonia
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::970324b3fcc52a9e34a97f5cdb396435
https://doi.org/10.1016/j.jorganchem.2010.08.032
https://doi.org/10.1016/j.jorganchem.2010.08.032
Publikováno v:
Journal of Organometallic Chemistry. 694:3674-3678
The reaction of alkanoyl chlorides with arylstannanes in 1,2-dichlorobenzene (180 °C) is a simple and direct route for the catalyst-free and regioselective synthesis of tertiary alkyl aryl ketones in good to excellent isolated yields (55–77%). Nev
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f570f6336ba96c7bd8630267c391a23f
https://doi.org/10.1016/j.jorganchem.2009.07.019
https://doi.org/10.1016/j.jorganchem.2009.07.019
Autor:
Mercedes A. Badajoz, Marcos J. Lo Fiego, Maria T. Lockhart, Gustavo F. Silbestri, Alicia B. Chopa
Publikováno v:
The Journal of Organic Chemistry. 73:9184-9187
The exceptional leaving group ability of the trimethylstannyl group in electrophilic aromatic substitutions makes possible the synthesis, in a single step, of bi- and triaroylarenes through the catalyst-free, regioselective reaction of bi- and trista
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f774734df107524d5ba5d05e5abb9d50
https://doi.org/10.1021/jo801890e
https://doi.org/10.1021/jo801890e
Publikováno v:
Journal of Organometallic Chemistry. 693:2458-2462
The reaction of trimethyltinsodium ( 1 ) with 1-(diethoxyphosphoryl)oxy-1,3-cyclohexadienes in liquid ammonia under irradiation affords the corresponding 1-trimethylstannylcyclohexadienes. We suggest that these reactions occur by an S RN 1 mechanism.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6b6f561b04e706ae9fe520e02e729bc7
https://doi.org/10.1016/j.jorganchem.2008.04.018
https://doi.org/10.1016/j.jorganchem.2008.04.018
Publikováno v:
Journal of Organometallic Chemistry. 691:1520-1524
A series of diaryl ketones have been synthesized in good yields (40–78%) through the catalyst-free reaction of trimethylarylstannanes with aroyl chlorides in chlorobenzene as solvent. In addition, an attractive feature is that these reactions are c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0092cda1aa78b373bd491a9a5009f797
https://doi.org/10.1016/j.jorganchem.2005.12.027
https://doi.org/10.1016/j.jorganchem.2005.12.027
Publikováno v:
The Journal of Organic Chemistry. 69:3801-3805
Ketones are converted into vinyl diethyl phosphate esters (VinDEP), which under photostimulation reacted with sodium trimethylstannide (1) or sodium triphenylstannide (2) in liquid ammonia affording vinylstannanes via a vinylic S(RN)1 mechanism. Thus
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::42aab87ac7ba6bc0873e7c9bc58fd1be
https://doi.org/10.1021/jo049762t
https://doi.org/10.1021/jo049762t
Publikováno v:
Organometallics. 21:1425-1429
Phenols are converted into aryl diethyl phosphate esters (ArDEP), which on reaction with sodium trimethylstannide (1) or sodium triphenylstannide (2) in liquid ammonia afford arylstannanes by the S R N 1 mechanism. Thus, the photostimulated reaction
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ad242d5f353bad2f00790ff5d5a1cb3c
https://doi.org/10.1021/om010878e
https://doi.org/10.1021/om010878e
Publikováno v:
Proceedings of The 18th International Electronic Conference on Synthetic Organic Chemistry.
The use of aryl azides as synthetic intermediates has attracted much attention due to their potential applications in organic and bioorganic chemistry. Because of their relatively high stability, these compounds have found biological and industrial u
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::2463b15490fc200be2b9549ab170c78d
https://doi.org/10.3390/ecsoc-18-a049
https://doi.org/10.3390/ecsoc-18-a049