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Autor:
Rowshan Ara Begum, Vanessa Raco, Christopher J. Dares, A. B. P. Lever, Maria Kapovsky, Elaine S. Dodsworth
Publikováno v:
Inorganic Chemistry. 52:169-181
The complex Ru(II)(NH(3))(2)(o-benzoquinonediimine)Cl(2) undergoes a reversible apparent acid/base reaction, although it has no obvious basic lone pairs. The reaction is a proton-assisted disproportionation yielding an oxidant ([Ru(III)(NH(3))(2)(o-b