Cluster Core Isomerism Induced by Crystal Packing Effects in the [HCo15Pd9C3(CO)38]2– Molecular Nanocluster

Autor: Beatrice Berti, Iacopo Ciabatti, Cristina Femoni, Maria Carmela Iapalucci, Stefano Zacchini

Publikováno v: ACS Omega, Vol 3, Iss 10, Pp 13239-13250 (2018)

Externí odkaz: https://doaj.org/article/0c0053262a3842628230d67f7f5a3f23

Atomically Precise Platinum Carbonyl Nanoclusters: Synthesis, Total Structure, and Electrochemical Investigation of [Pt27(CO)31]4– Displaying a Defective Structure

Autor: Cristiana Cesari, Beatrice Berti, Tiziana Funaioli, Cristina Femoni, Maria Carmela Iapalucci, Daniele Pontiroli, Giacomo Magnani, Mauro Riccò, Marco Bortoluzzi, Federico Maria Vivaldi, Stefano Zacchini

Publikováno v: Inorganic Chemistry. 61:12534-12544

The molecular Pt nanocluster [Pt27(CO)31]4- (14-) was obtained by thermal decomposition of [Pt15(CO)30]2- in tetrahydrofuran under a H2 atmosphere. The reaction of 14- with increasing amounts of HBF4·Et2O afforded the previously reported [Pt26(CO)32

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c6aa241a9b670b98b4d3866bcb34ec5f
https://doi.org/10.1021/acs.inorgchem.2c00965

Thermal Growth of Au–Fe Heterometallic Carbonyl Clusters Containing N-Heterocyclic Carbene and Phosphine Ligands

Autor: Maria Carmela Iapalucci, Beatrice Berti, Cristiana Cesari, Cristina Femoni, Marco Bortoluzzi, Federico Vacca, Rita Mazzoni, Stefano Zacchini

Publikováno v: Inorganic Chemistry

The thermal reactions of [NEt4][Fe(CO)4(AuNHC)] [NHC = IMes ([NEt4][1]) or IPr ([NEt4][2]); IMes = C3N2H2(C6H2Me3)2; IPr = C3N2H2(C6H3iPr2)2], Fe(CO)4(AuNHC)2 [NHC = IMes (3) or IPr (4)], Fe(CO)4(AuIMes)(AuIPr) (5), and Fe(CO)4(AuNHC)(AuPPh3) [NHC =

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5e41d8e6d62a5c6e1c2acbab1a84ec67
https://doi.org/10.1021/acs.inorgchem.9b02912

2-D Molecular Alloy Ru-M (M = Cu, Ag, and Au) Carbonyl Clusters: Synthesis, Molecular Structure, Catalysis, and Computational Studies

Autor: Cristiana Cesari, Marco Bortoluzzi, Francesca Forti, Lisa Gubbels, Cristina Femoni, Maria Carmela Iapalucci, Stefano Zacchini

The reactions of [HRu3(CO)11]- (1) with M(I) (M = Cu, Ag, and Au) compounds such as [Cu(CH3CN)4][BF4], AgNO3, and Au(Et2S)Cl afford the 2-D molecular alloy clusters [CuRu6(CO)22]- (2), [AgRu6(CO)22]- (3), and [AuRu5(CO)19]- (4), respectively. The rea

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::3f4cef2cf3c18129c03d5b654ad7342d
https://hdl.handle.net/10278/5007600

Inverted Ligand Field in a Pentanuclear Bow Tie Au/Fe Carbonyl Cluster

Autor: Gabriele Manca, Fabrizia Fabrizi de Biani, Maddalena Corsini, Cristiana Cesari, Cristina Femoni, Maria Carmela Iapalucci, Stefano Zacchini, Andrea Ienco

Publikováno v: Inorganic chemistry (Online) 61 (2022): 3484–3492. doi:10.1021/acs.inorgchem.1c03386
info:cnr-pdr/source/autori:Gabriele Manca, Fabrizia Fabrizi de Biani, Maddalena Corsini, Cristiana Cesari, Cristina Femoni, Maria Carmela Iapalucci, Stefano Zacchini, Andrea Ienco/titolo:Inverted Ligand Field in a Pentanuclear Bow Tie Au%2FFe Carbonyl Cluster/doi:10.1021%2Facs.inorgchem.1c03386/rivista:Inorganic chemistry (Online)/anno:2022/pagina_da:3484/pagina_a:3492/intervallo_pagine:3484–3492/volume:61

Gold chemistry has experienced in the last decades exponential attention for a wide spectrum of chemical applications, but the +3 oxidation state, traditionally assigned to gold, remains somewhat questionable. Herein, we present a detailed analysis o

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f79c55c4b1c343e7617a18549dda0c9c