Screening Approach for Identifying Cocrystal Types and Resolution Opportunities in Complex Chiral Multicomponent Systems

Autor: Joop H. ter Horst, Paul Tinnemans, Herman J. M. Kramer, Hugo Meekes, René de Gelder, Weiwei Li, Mariëtte de Groen

Publikováno v: Crystal Growth & Design, 21, 112-124
Crystal Growth & Design, 21, 1, pp. 112-124

Cocrystallization of racemic-compound-forming chiral molecules can result in conglomerate cocrystals or diastereomerically related cocrystals, which enable the application of chiral separation techniques such as preferential crystallization and class

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9f6e89276798ecce0fdcea14e96445e7
https://doi.org/10.1021/acs.cgd.0c00890

High-pressure electrochemical reduction of CO2 to formic acid/formate: effect of pH on the downstream separation process and economics

Autor: Wiebren de Jong, Antero Laitinen, Erdem Irtem, J. P. Martin Trusler, Andrew R. T. Morrison, Thijs J. H. Vlugt, Robert de Kler, Mariëtte de Groen, Rien van Haperen, Leo J. P. van den Broeke, Tom Breugelmans, Mahinder Ramdin

Publikováno v: Industrial and Engineering Chemistry Research, 58(51)
Industrial and engineering chemistry research
Ramdin, M, Morrison, A R T, De Groen, M, Van Haperen, R, De Kler, R, Irtem, E, Laitinen, A T, Van Den Broeke, L J P, Breugelmans, T, Trusler, J P M, Jong, W D & Vlugt, T J H 2019, ' High-Pressure Electrochemical Reduction of CO 2 to Formic Acid/Formate : Effect of pH on the Downstream Separation Process and Economics ', Industrial and Engineering Chemistry Research, vol. 58, no. 51, pp. 22718-22740 . https://doi.org/10.1021/acs.iecr.9b03970

We use a high-pressure semicontinuous batch electrochemical reactor with a tin-based cathode to demonstrate that it is possible to efficiently convert CO2 to formic acid (FA) in low-pH (i.e., pH < pKa) electrolyte solutions. The effects of CO2 pressu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0e5862af030c9780f1b28dbe53fb89a9
http://hdl.handle.net/10044/1/77562

High pressure electrochemical reduction of CO2 to formic acid/formate: A comparison between bipolar membranes and cation exchange membranes

Autor: Wiebren de Jong, Mahinder Ramdin, Andrew R. T. Morrison, Robert de Kler, J. P. Martin Trusler, Thijs J. H. Vlugt, Rien van Haperen, Mariëtte de Groen, Leo J. P. van den Broeke

Publikováno v: Industrial and Engineering Chemistry Research, 58(5)
Industrial & Engineering Chemistry Research

A high pressure semicontinuous batch electrolyzer is used to convert CO2 to formic acid/formate on a tin-based cathode using bipolar membranes (BPMs) and cation exchange membranes (CEMs). The effects of CO2 pressure up to 50 bar, electrolyte concentr

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ff89e5fdc56f31b2632dbdc08d233500
http://resolver.tudelft.nl/uuid:af73613e-3ba4-44c2-b0b3-c091e104903d

Phase behaviour of the system 4′-pentyloxy-4-cyanobiphenyl+CO2

Autor: Theo W. de Loos, Thijs J. H. Vlugt, Hiroyuki Matsuda, Mariëtte de Groen

Publikováno v: The Journal of Chemical Thermodynamics. 59:20-27

Isoplethic phase diagrams were measured for the system 4′-pentyloxy-4-cyanobiphenyl + CO 2 for CO 2 mole fractions up to 0.72, in temperature range 280–360 K and at pressures up to 12 MPa using a synthetic method with visual observation. It is fo

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::e6f4b23fff25af28dc87574e14ba1f14
https://doi.org/10.1016/j.jct.2012.11.026

Highly active and selective precious metal catalysts by use of the reduction-deposition method

Autor: Peter H. Berben, Peter T. Witte, Pablo Bakermans, Ralph M. de Rooij, John W. Geus, Mariëtte de Groen, Hans G. Donkervoort

New mono- and bimetallic precious metal catalysts are prepared by reduction-deposition, in a way that is suitable for large scale production. The preparation is done in water, without the use of any organic solvents and makes use of commercially avai

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a95fa1dfac896fae5fc227c200f7864f
https://doi.org/10.1016/s0167-2991(10)75017-5