Zobrazeno 1 - 6
of 6
pro vyhledávání: '"Margherita Pirola"'
Publikováno v:
Molecules, Vol 24, Iss 12, p 2260 (2019)
A stereoselective synthetic strategy for the preparation of trifluoromethylamine mimics of retro-thiorphan, involving a diastereoselective, metal-free catalytic step, has been studied in batch and afforded the target molecule in good yields and high
Externí odkaz:
https://doaj.org/article/8822a27dd1514cc399e062b9358cfac2
Metal-Free Alpha Trifluoromethylselenolation of Carbonyl Derivatives under Batch and Flow Conditions
Publikováno v:
Molecules, Vol 24, Iss 4, p 726 (2019)
Trifluoromethylselenolated carbonyl compounds represent an emerging class with potential applications in several fields; however, a widespread use of such compound is hampered by the very limited number of strategies for their preparation. In this st
Externí odkaz:
https://doaj.org/article/6ad8758dd02c41259dc0c7ce3e13f88a
Publikováno v:
European Journal of Organic Chemistry. 2020:4641-4651
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 27(40)
A metal-free, mild and chemodivergent transformation involving nitroalkanes has been developed. Under optimized reaction conditions, in the presence of trichlorosilane and a tertiary amine, aliphatic nitroalkanes were selectively converted into amine
Autor:
Margherita Pirola, Alessandra Puglisi, Maurizio Benaglia, Laura Raimondi, Maria Elena Compostella
Publikováno v:
Synthesis. 50:1430-1438
The enantioselective organocatalytic reduction of aryl-substituted nitroenamines was successfully performed under continuous-flow conditions. After a preliminary screening with a 10-μL microreactor, to establish the best reaction conditions, the red
Publikováno v:
Repositório Científico de Acesso Aberto de Portugal (Repositórios Cientìficos)
Agência para a Sociedade do Conhecimento (UMIC)-FCT-Sociedade da Informação
instacron:RCAAP
Agência para a Sociedade do Conhecimento (UMIC)-FCT-Sociedade da Informação
instacron:RCAAP
The diastereoselective, trichlorosilane-mediate reduction of imines, bearing different and removable chiral auxiliaries, in combination either with achiral bases or catalytic amounts of chiral Lewis bases, was investigated to afford immediate precurs