Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Marek Piechowicz"'
Publikováno v:
The Journal of Physical Chemistry B. 125:6629-6638
Solution structure in liquid-liquid extraction affects the efficacy of separation; however, even for simplified organic phases, structural characterization and attribution of aggregation to intermolecular interactions are fundamental challenges. We i
Publikováno v:
Physical Chemistry Chemical Physics. 23:8880-8890
The molecular and nanoscale origins of nonideality in excess thermodynamic properties are essential to understanding cosolvent mixtures, yet they remain challenging to determine. Here, we consider a binary mixture of water and an amphiphile, N,N,N',N
Publikováno v:
ChemPhysChem. 21:1157-1165
Polymerized high internal phase emulsions (poly(HIPE)s) are porous polymer monoliths whose synthesis can easily be tailored to allow incorporation of functional units. In this work, nitrile containing poly(HIPE)s have been prepared with either acrylo
Publikováno v:
The journal of physical chemistry. B. 124(47)
The role of different intermolecular interactions in the aggregation of amphiphiles in an organic solvent is studied for systems of relevance to liquid-liquid extraction (LLE), a chemical process used to selectively recover metals from complex mixtur
Publikováno v:
Dalton Transactions. 47:5348-5358
Uptake characteristics of a bis-amidoximated polymer are presented for 90Sr2+, 137Cs+, and 233UO22+ to assess rational ligand design and polymer engineering efforts applied to selective uranium extraction. Functionalized with the bis-amidoxime diaryl
Autor:
Wenbin Lin, Aiguo Hu, Samuel S. Veroneau, Nathan C. Thacker, James C. Gilhula, Carter W. Abney, Marek Piechowicz, Youfu Wang
Publikováno v:
ACS Applied Materials & Interfaces. 9:27894-27904
The amidoxime group (−RNH2NOH) has long been used to extract uranium from seawater on account of its high affinity toward uranium. The development of tunable sorbent materials for uranium sequestration remains a research priority as well as a signi
Autor:
Gary A. Gill, Jordana R. Wood, Carter W. Abney, Wenbin Lin, Sadananda Das, Zekai Lin, Li-Jung Kuo, Marek Piechowicz, Sheng Dai, Richard T. Mayes
Publikováno v:
Physical Chemistry Chemical Physics. 18:23462-23468
The development of technology to harvest the uranium dissolved in seawater would enable access to vast quantities of this critical metal for nuclear power generation. Amidoxime polymers are the most promising platforms for achieving this separation,
Autor:
Marek Piechowicz, Zekai Lin, Gabriel M. Veith, Carter W. Abney, Vyacheslav S. Bryantsev, Wenbin Lin, Richard T. Mayes, Sheng Dai
Publikováno v:
Energy & Environmental Science. 9:448-453
Limited resource availability and population growth have motivated interest in harvesting valuable metals from unconventional reserves, but developing selective adsorbents for this task requires structural knowledge of metal binding environments. Ami
Publikováno v:
Industrial & Engineering Chemistry Research. 55:4170-4178
Informed by density functional theory calculations, a novel bifunctional chelator, (Z)-2-[2-(N′-hydroxycarbamimidoyl)phenoxy]benzoic acid, was designed and synthesized for ultrahigh uranium uptake from seawater. Investigation of the ligand for uran
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 47(15)
Uptake characteristics of a bis-amidoximated polymer are presented for 90Sr2+, 137Cs+, and 233UO22+ to assess rational ligand design and polymer engineering efforts applied to selective uranium extraction. Functionalized with the bis-amidoxime diaryl