Zobrazeno 1 - 10
of 48
pro vyhledávání: '"Marek Matlengiewicz"'
Publikováno v:
Polymer Bulletin. 76:6291-6303
Several new random copolyethers of styrene oxide (SO) and other monosubstituted oxirane as comonomer, i.e., propylene oxide (PO), isopropyl glycidyl ether (IPGE) or allyl glycidyl ether (AGE), were synthesized in THF solution at room temperature. As
Publikováno v:
International Journal of Polymer Analysis and Characterization. 23:545-565
Analysis of carbonyl and β-CH2 signals in the 100 MHz 13C NMR spectra of poly(methyl methacrylate-co-n-propyl acrylate) (PMMA/nPrA), provided distribution of configurational-compositional s...
Autor:
Radosław Kozak, Marek Matlengiewicz
Publikováno v:
Polymer Testing. 64:20-37
The influence of interaction enthalpy (ΔHMOD/BuLi) of μ, σ, σ+μ and σ-μ complexing polar modifiers with n-butyllithium on the 1,3-butadiene anionic polymerization enthalpy (ΔHBD), polymerization reaction rate (kp) and polybutadiene microstruc
Publikováno v:
Polymer Bulletin. 75:1101-1121
Anionic polymerization of propylene oxide was carried out in the presence of two groups of potassium salts activated 18-crown-6 (18C6), e.g. alkoxide salts (CH3OK, i-PrOK, t-BuOK, CH3OCH2CH(CH3)OK, KCH2O) and other salts (CbK, Ph3CK, Ph2PK, Ph3HBK, K
Autor:
Danuta Kwapulińska, Kinga Skrzeczyna, Marek Matlengiewicz, Sylwia Golba, Justyna Jurek-Suliga, Zbigniew Grobelny
Publikováno v:
Polymer Bulletin. 74:4763-4780
It was stated that initiation in ring opening polymerization of styrene oxide depends on the kind of potassium alkoxide activated by 18-crown-6 used. In the presence of potassium methoxide the oxirane ring opening occurs exclusively in the β-positio
Autor:
Radosław Kozak, Marek Matlengiewicz
Publikováno v:
International Journal of Polymer Analysis and Characterization. 22:51-61
A comparison was performed of the influence of polar modifiers forming (separately or simultaneously) σ and μ complexes with a living center during anionic polymerization of 1,3-butadiene — regarding the content and distribution of butadiene isom
Publikováno v:
International Journal of Polymer Analysis and Characterization. 21:728-748
The distribution of configurational–compositional sequences of poly(methyl methacrylate-co-isopropyl acrylate) (PMMA/iPrA) has been determined from the carbonyl and β-CH2 signals in the 100 MHz 13C NMR spectra of the copolymer. The carbonyl signal
Publikováno v:
International Journal of Polymer Analysis and Characterization. 21:69-76
An incremental method for characterizing triad and pentad distribution by 13C NMR spectroscopy was applied to the poly(methyl methacrylate-co-isobutyl acrylate) copolymer. Calculation of the intensity of individual lines was performed applying Bernou
Autor:
Marek Matlengiewicz, Radosław Kozak
Publikováno v:
International Journal of Polymer Analysis and Characterization. 21:59-68
The influence of acid-base polar modifiers (σ-μ complex): amine-alkoxide, amine-ether-alkoxide, and ether-alkoxide complexes on microstructure of polybutadiene obtained by anionic polymerization was studied. The content of butadiene isomeric struct
Autor:
Marek Matlengiewicz, Radosław Kozak
Publikováno v:
International Journal of Polymer Analysis and Characterization. 21:44-58
The influence of mixtures of sodium mentholate (SMT) as a Lewis acid polar modifier and different Lewis base polar modifiers (amines, amine-ethers, ethers) on the microstructure of polybutadiene obtained by anionic polymerization was studied and comp