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pro vyhledávání: '"Marcus A Juhasz"'
Autor:
Austin A Kamin, Marcus A. Juhasz
Publikováno v:
Inorganic Chemistry. 59:189-192
The percyanated dodecaborate anion [B12(CN)12]2- was prepared by reacting [B12I12]2- with CuCN in the presence of a palladium catalyst at elevated pressure and temperature in a microwave reactor. The fully cyanated cluster was isolated as a tetraethy
Publikováno v:
Acta Crystallographica Section E, Vol 70, Iss 4, Pp o411-o412 (2014)
In the title compound, C8H20N+·C3H10B11N2−, the carborane anion cage displays nearly-perfect Cs symmetry, with the two CN groups lying on a noncrystallographic mirror plane that bisects the cage. In the crystal, the anions form extended chains alo
Externí odkaz:
https://doaj.org/article/13bd032275ac4798b959ed129321d6a9
Autor:
Ashlyn A, Kamin, Marcus A, Juhasz
Publikováno v:
Inorganic chemistry. 59(1)
The percyanated dodecaborate anion [B
Microwave-Assisted Iodination: Synthesis of Heavily Iodinated 10-Vertex and 12-Vertex Boron Clusters
Publikováno v:
Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 46:583-588
Microwave-assisted syntheses of heavily iodinated 10-vertex and 12-vertex closo boron clusters are reported. Salts of closo-B10I102−, 1-carba-closo-CHB9H4I5−, 1-carba-closo-CB11H6I6−, 1-carba-closo-CHB11I11−, and B12I122− were prepared in y
Autor:
Marcus A. Juhasz, Gregory E. Dwulet
Publikováno v:
Inorganic Chemistry Communications. 51:26-28
The dicarboxylic acid, 7,12-(COOH)2-CB11H10−, was prepared and characterized by NMR, IR, MS, and single-crystal X-ray diffraction. Titration studies reveal that 7,12-(COOH)2-CB11H10− has a pKa of > 6.35, indicating that this is a significantly we
Publikováno v:
Acta Crystallographica Section E, Vol 70, Iss 4, Pp o411-o412 (2014)
Acta Crystallographica Section E: Structure Reports
Acta Crystallographica Section E: Structure Reports
In the title compound, C8H20N+·C3H10B11N2−, the carborane anion cage displays nearly-perfectCssymmetry, with the two CN groups lying on a noncrystallographic mirror plane that bisects the cage. In the crystal, the anions form extended chains along