Zobrazeno 1 - 10
of 75
pro vyhledávání: '"Marco Wendorff"'
Publikováno v:
Crystals, Vol 10, Iss 11, p 1052 (2020)
The Ga-rich gallides of the alkali metals present an interesting, yet still scarcely investigated case of polyanionic cluster compounds with subtle variations in the character of their chemical bonding. In the present work, the Ga richest phases K3Ga
Externí odkaz:
https://doaj.org/article/afc8d092beda436095209ebbc678dab8
Publikováno v:
Crystals
Volume 10
Issue 11
Crystals, Vol 10, Iss 1052, p 1052 (2020)
Volume 10
Issue 11
Crystals, Vol 10, Iss 1052, p 1052 (2020)
The Ga-rich gallides of the alkali metals present an interesting, yet still scarcely investigated case of polyanionic cluster compounds with subtle variations in the character of their chemical bonding. In the present work, the Ga richest phases K3Ga
Autor:
Marco Wendorff, Caroline Röhr
Publikováno v:
Zeitschrift für Kristallographie - Crystalline Materials. 233:515-529
The alkaline-earth tri-mercurides AHg3 (A=Ca, Sr, Ba) were yielded from stoichiometric melts of the elements in pure phase (in the case of Sr with Sr11Hg54 as a by-product) and their structures were determined by means of single crystal X-ray data. A
Publikováno v:
Zeitschrift für Kristallographie - Crystalline Materials. 232:515-541
In a systematic synthetic, crystallographic and bond theoretical study, the stability ranges as well as the distribution of the isoelectronic late d-block elements Zn, Cd and Hg (M) in the polyanions of the YCd6-type phases (Ca/Sr)Cd6 have been inves
Autor:
Marco Wendorff, Caroline Röhr
Publikováno v:
Zeitschrift für Naturforschung B. 70:265-277
Starting from the new compound SrHg2Sn2, which is isoelectronic and also isotypic to the indide SrIn4, the successive substitution of Sn against the electron poor Hg has been investigated in a combined synthetic, crystallographic, and bond-theoretica
Autor:
Caroline Röhr, Marco Wendorff
Publikováno v:
Zeitschrift für Naturforschung B. 69:388-408
In a combined synthetic, X-ray single-crystal and bond-theoretical study the phase widths of SrIn4 and the related Sr3In11 upon a sucessive substitution of indium against the more electronpoor, more electronegative and only slightly smaller element m
Autor:
Caroline Röhr, Marco Wendorff
Publikováno v:
Zeitschrift für Naturforschung B. 68:307-322
The systematic experimental and bond-theoretical study of the phase width of the BaAl4 structure type in the ternary system BaIn4- BaHg4 shows that this structure type is stable up to BaIn1:7Hg2:3 (tetragonal, tI10, space group I4=mmm, a=474.2(3), c=
Autor:
Caroline Röhr, Marco Wendorff
Publikováno v:
Journal of Alloys and Compounds. 546:320-328
The new binary barium mercuride BaHg 6 and the derived ternary indium and gallium containing compounds BaIn 1.2 Hg 4.8 and BaGa 0.8 Hg 5.2 were synthesized from melts of the elements, which were slowly cooled from 500 to 200 °C. Their crystal struct
Publikováno v:
Journal of Solid State Chemistry. 196:416-424
The title compounds Ba{sub 3}ZnHg{sub 10} and BaZn{sub 0.6}Hg{sub 3.4} were synthesized from stoichiometric ratios of the elements in Ta crucibles. Their crystal structures, which both represent new structure types, have been determined using single
Autor:
Caroline Röhr, Marco Wendorff
Publikováno v:
Zeitschrift für Naturforschung B. 67:893-906
Ba20Hg103, the next Hg-rich binary barium mercuride after BaHg11 and BaHg6, was synthesized from melts of the elements, which were slowly cooled from 550 to 200 °C. It forms a new complex cubic structure type (F43m, a = 2333.30(10) pm, Z = 4, R1 = 0