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Publikováno v:
Dalton Transactions. 51:12334-12351
Monodentate aminophosphanes HNP [NH(4-tolyl)PPh2] and SiMe3NP [SiMe3N(4-tolyl)PPh2] react with [Ir(μ-Cl)(cod)]2 affording tetra- or pentacoordinate complexes of formula [IrCl(L)n(cod)] (L = HNP, n = 1, 2; L = SiMe3NP, n = 1). The reaction of [IrCl(S
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 51(18)
The iridium(III) hydride compound [IrH{κ3C,P,P′-(SiNP–H)}(CNtBu)2][PF6] (1PF6) was obtained by reaction of [Ir(SiNP)(cod)][PF6] with CNtBu as the result of the intramolecular oxidative addition of the SiCH2–H bond to iridium(I) [SiNP = Si(CH3)