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pro vyhledávání: '"Marco Filippelli"'
Autor:
Marco Filippelli
Publikováno v:
Chemosphere. 39:1199-1210
A feasibility study to prepare a reference material of methyl mercury (MeHg) is reported. The dry sediment was tested with different solutions to understand how MeHg is bond to sediment matrix. For this we have tested the sediment with water, where a
Publikováno v:
Microbial ecology. 17(3)
One hundred six strains of aerobic bacteria were isolated from the Fiora River which drains an area of cinnabar deposits in southern Tuscany, Italy. Thirty-seven of the strains grew on an agar medium containing 10μg/ml Hg (as HgCl2) with all of thes
Publikováno v:
Water, Air, & Soil Pollution. 80:805-815
Autor:
Marco Filippelli
Publikováno v:
Applied Organometallic Chemistry. 8:687-691
A method of detecting methylmercury species (MeHg) and dimethylmercury (DMM) has been studied. MeHg was transformed prior to its determination as methylmercury hydride (MMH) by use of NaBH4. The two volatile forms of organic mercury were detected by
Publikováno v:
Environmental sciencetechnology. 22(7)
A sensitive and specific technique, gas chromatography/Fourier transform infrared spectroscopy (GC/FTIR), has been used to detect traces of methane from the biodegradation of methylmercury due to the detoxification process of Pseudomonas putida strai
Autor:
Franco Baldi, Marco Filippelli
Publikováno v:
Applied Organometallic Chemistry. 7:487-493
A new approach was used to determine the reaction products of methylcobalamin and ionic mercury: purge-and-trap gas chromatography in line with Fourier transform infrared spectroscopy (PT GCIFTIR). This technique simultaneously and specifically deter
Autor:
Franco Baldi, Marco Filippelli
Publikováno v:
ChemInform. 25
A new approach was used to determine the reaction products of methylcobalamin and ionic mercury: purge-and-trap gas chromatography in line with Fourier transform infrared spectroscopy (PT GCIFTIR). This technique simultaneously and specifically deter
Publikováno v:
Environmental Science & Technology. 26:1457-1460
We report a novel aqueous derivatization of methylmercury chloride by NaBH 4 to mehtymercury hydride (CH 3 HgH), a volatile and unexpectedly stable species which we determined has a half-life of approximately 2 h. The analytical apparatus consisted o
Publikováno v:
Water Air & Soil Pollution. 56:465-475
Bacteria are resistant to Hg compounds by virtue of two specific enzymes: mercuric reductase and organomercurial lyase. We investigate these specific enzyme systems 1) to determine McHg in biological samples by its enzymatic transformation to the res
Autor:
Marco Filippelli, Franco Baldi
Publikováno v:
Environmental Science & Technology. 25:302-305
A new method is suggested for determining methylmercury in biological samples. The determination is based on the use of whole cells of a broad-spectrum mercury-resistant bacterium, Pseudomonas putida, strain FB1, which is induced to produce the enzym