Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Marcello DiMare"'
Publikováno v:
e-EROS Encyclopedia of Reagents for Organic Synthesis
[7440-02-0] Ni (MW 58.71) InChI = 1S/Ni InChIKey = PXHVJJICTQNCMI-UHFFFAOYSA-N (hydrogenolyses and hydrogenations1) Physical Data: mp 1453 °C; bp 2730 °C; d 8.908 g cm−3. Form Supplied in: powder, rod, wire, foil, or pellet; activated nickel is n
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::459b42d3d7d23d9f4e57faea3614f148
https://doi.org/10.1002/047084289x.rn011.pub2
https://doi.org/10.1002/047084289x.rn011.pub2
Autor:
Marcello DiMare
Publikováno v:
The Journal of Organic Chemistry. 61:8378-8385
Calculations of the energies and geometries of various complexes of diborane and borane with acetaldehyde, acetone, acetyl chloride, formaldehyde, methyl acetate, THF, dimethyl sulfide (DMS), and ammonia have been performed. Adducts and transition st
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::74288119da7f72396e3e98af53321c2a
https://doi.org/10.1021/jo961159q
https://doi.org/10.1021/jo961159q
Publikováno v:
The Journal of Organic Chemistry. 61:868-873
Syn-selective reduction protocols for β-hydroxy ketones are described exploiting the intermediacy of titanium and boron chelates derived from TiCl4 and BCl3, respectively. Reductions are conducted at −78 °C in CH2Cl2 using a wide range of CH2Cl2-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e81c2cc7f64183d479f6fc0fccfae099
https://doi.org/10.1021/jo951549x
https://doi.org/10.1021/jo951549x
Publikováno v:
The Journal of Organic Chemistry. 60:1777-1787
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e560d61d526c1f5bf0c987d455e8cfff
https://doi.org/10.1021/jo00111a041
https://doi.org/10.1021/jo00111a041
Autor:
Craig W. Lindsley, Marcello DiMare
Publikováno v:
Tetrahedron Letters. 35:5141-5144
Catalytic quantities of transition metal alkoxides such as Ti(O i Pr) 4 have been found to accelerate dramatically the rate of catecholborane and BH 3 ·THF reductions of ketones. Experiments suggest catalysis is achieved by the formation of alkoxybo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::92f1f395a308019eefcadf68a4bb4734
https://doi.org/10.1016/s0040-4039(00)77048-1
https://doi.org/10.1016/s0040-4039(00)77048-1
Publikováno v:
The Journal of Organic Chemistry. 59:523-527
The reduction of salicylaldehyde by pyridine-borane complex (PB) is much faster than that of other substituted benzaldehydes and ketones (seconds vs hours). Experiments reveal that this acceleration is due to an autocatalytic process involving a pyri
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::22a9539059e7404a4550e8ddd7ce055f
https://doi.org/10.1021/jo00082a006
https://doi.org/10.1021/jo00082a006
Autor:
David Tobia, Thomas L. White, Marcello DiMare, Bruce Rickborn, Brian L Phillips, Roy Harrison
Publikováno v:
The Journal of Organic Chemistry. 58:6701-6706
Many years ago Diels and Thiele noted the unusual stability of maleic anhydride cycloadducts and employed the feature in scavenging anthracene generated in a retro-[4+2] reaction. N-methyl-maleimide, although nearly identical to maleic anhydride in r
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::dc4834c1efb1fbbd431823d2573356a3
https://doi.org/10.1021/jo00076a032
https://doi.org/10.1021/jo00076a032
Publikováno v:
ChemInform. 25
A new chelation-controlled, α-chiral ketone reduction protocol is presented based on titanium tetrachloride and a wide variety of reducing agents. Features of the proposed intermediate titanium chelates necessary to obtain high diastereoselectivity
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::dff542e54e9dcd158bcd2ebc56314d82
https://doi.org/10.1002/chin.199429082
https://doi.org/10.1002/chin.199429082
Autor:
Marcello DiMare, Craig W. Lindsley
Publikováno v:
ChemInform. 25
Catalytic quantities of transition metal alkoxides such as Ti(O i Pr) 4 have been found to accelerate dramatically the rate of catecholborane and BH 3 ·THF reductions of ketones. Experiments suggest catalysis is achieved by the formation of alkoxybo
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::bee5500194047beda0cf4170ee3b1910
https://doi.org/10.1002/chin.199448083
https://doi.org/10.1002/chin.199448083
Publikováno v:
ChemInform. 27
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::1a142c3a143bd4fdd8b93362f255711d
https://doi.org/10.1002/chin.199603055
https://doi.org/10.1002/chin.199603055