Zobrazeno 1 - 10
of 249
pro vyhledávání: '"Marcel Sergent"'
Publikováno v:
Journal of Solid State Chemistry. 155:250-258
The structures of nickel sulfoselenide Chevrel phases have been determined. All the richest nickel phases crystallize in rhombohedral symmetry. A single-crystal structural study makes it possible to identify the special nickel cation locations inside
Publikováno v:
Materials Research Bulletin. 35:151-168
Three different types of pseudo-binary Mo 6 Se 8−x S x Chevrel phases series have been reported in the literature. Confusion among them has existed, although two of them are metastable series. We present a new study of these series, based on their
Publikováno v:
Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry. 2:661-667
The replacement of a small amount of chlorine by fluorine has made it possible to synthesize Nb6Cl15 − xFxin chlorofluoride with the Ta6Cl15 structure-type. The crystal structures of two compositions in the solid solution (x = 2.2 (I) and x = 4.4 (
Publikováno v:
Journal of Solid State Chemistry. 147:358-365
A trivalent cluster unit has been synthesized by the solid-state route for the first time in the Rb–Re–S–Br system. The new rhombohedral compound Rb3Re6S7Br7 is built from octahedral Re6 clusters surrounded by two μ3-Si and six μ3-Li ligands
Publikováno v:
Journal of Solid State Chemistry. 147:199-210
In this paper, we present a comparative electrochemical study of copper insertion into series of Mo 6 Se 8− x S x phases which are obtained through different synthesis processes. We show that α -, β -, and HT-forms can reversibly accommodate copp
Publikováno v:
Journal of Solid State Chemistry. 147:350-357
Two new series of Ta 6 chlorides, Cs 2 M ′ II Ta 6 Cl 18 and Cs M ′ II Ta 6 Cl 18 , have been isolated with M ′=Ba 2+ , Pb 2+ , Sr 2+ , Eu 2+ , Ca 2+ . From single-crystal structure refinements the compounds Cs 2 PbTa 6 Cl 18 [ R -3, Z =1, a =1
First Example of Molybdenum Atoms in the Network of High Temperature Chevrel Phases: Moy[Mo6Se8+xSx]
Publikováno v:
Journal of Solid State Chemistry. 145:159-166
In the literature Mo6Se8−xSx (0≤x≤4) Chevrel phase binaries are stable compounds, synthesized by solid state reaction from stoichiometric mixture of MoS2, MoSe2, and Mo powders at 1200°C. We report the single-crystal structure of these compoun
Autor:
Vanina Tranchant, Richard Retoux, Yvon Laligant, Marcel Sergent, Michel Decroux, S. Even-Boudjada, Roger Chevrel, Marie-Pierre Crosnier-Lopez
Publikováno v:
Materials Letters. 38:90-97
The grain surfaces of PbMo 6 S 8 , (Pb,Sn)Mo 6 S 8 , and SnMo 6 S 8 high magnetic field Chevrel-phase superconductors have been investigated by high-resolution electron microscopy. Our investigations have shown that the grain surface of PbMo 6 S 8 ex
Publikováno v:
Journal of Solid State Chemistry. 141:140-148
In the search for defects in crystals of the cluster compound Cs2YbNb6Br18, polysynthetic microtwinning was observed by electron diffraction and high-resolution electron microscopy (HREM), and the complete twin law could be determined. The twinning e
Publikováno v:
Materials Research Bulletin. 33:419-431
The authors have used a new ultrafine precursor, the Mo{sub 6}S{sub 8} binary sulfide, and ultrafine PbS and Mo powders ({approximately} 0.5--0.5 {micro}m) to prepare an original mixture for PbMo{sub 6}S{sub 8} synthesis. The reaction of PbMo{sub 6}S