Zobrazeno 1 - 10
of 90
pro vyhledávání: '"Marcel Ovidiu Vlad"'
Publikováno v:
The Journal of Physical Chemistry A. 111:1844-1851
We develop a new method for obtaining connectivity data for nonlinear reaction networks, based on linear response experiments. In our approach the linear response is not the result of an approximation procedure but is due to the appropriate design of
Publikováno v:
Journal of Mathematical Physics. 45:736-760
We point out some interesting analogies between colored Levy noise and the random channel approach to disordered kinetics. These analogies are due to the fact that the probability density of the Levy noise source plays a similar role as the probabili
Publikováno v:
The Journal of Physical Chemistry B. 105:11710-11718
Autor:
Marcel Ovidiu Vlad, John Ross
Publikováno v:
Annual Review of Physical Chemistry. 50:51-78
▪ Abstract This paper reviews recent developments in the field of nonlinear chemical kinetics. Five topics are dealt with: (a) new approaches to complex reaction mechanisms, stoichiometric network analysis, classification of chemical oscillators an
Publikováno v:
The Journal of Physical Chemistry B. 103:3965-3974
We investigate a nonequilibrium biochemical network described in terms of transit time distributions. We assume that the network is made up of two subsystems which are connected to each other as well as to the environment. We evaluate the probability
Publikováno v:
The Journal of Physical Chemistry B. 103:1563-1580
Stretched exponential relaxation is the result of the existence of a large number of relaxation channels, any of them having a very small probability of being open. It is shown that the stretched exponential kinetics obeys a type of linear free energ
Publikováno v:
Physical Review E. 57:6497-6505
Publikováno v:
The Journal of Physical Chemistry B. 102:4598-4611
The large time behavior of the lifetime distributions of active intermediates is investigated for nonequilibrium chemical systems with stable limit cycles. The lifetime distributions are the soluti...
Publikováno v:
The Journal of Chemical Physics. 106:4157-4167
The paper deals with the relationships between the total rate of a relaxation process occurring in a system with static disorder and the decay rates attached to the different individual reaction channels. It is proven that the models of relaxation co
Publikováno v:
Physica Scripta. 54:581-593
The auence of the memory effects on the Poissonian clocks with fluctuating counting rates is investigated by using the technique of characteristic functionals. A general approach for computing all cumulants of the number of counts is suggested based