Zobrazeno 1 - 10 of 18 pro vyhledávání: '"Marcel Härterich"'
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Akademický článek
A step-for-step main-group replica of the Fischer carbene synthesis at a borylene carbonyl
Autor: Marcel Härterich, Alexander Matler, Rian D. Dewhurst, Andreas Sachs, Kai Oppel, Andreas Stoy, Holger Braunschweig
Publikováno v: Nature Communications, Vol 14, Iss 1, Pp 1-7 (2023)
Abstract The Fischer carbene synthesis, involving the conversion of a transition metal (TM)-bound CO ligand to a carbene ligand of the form [=C(OR’)R] (R, R’ = organyl groups), is one of the seminal reactions in the history of organometallic chem
Externí odkaz: https://doaj.org/article/dbab5c0d08d0411180aed3b43ba0cd1d
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2
Cyclic alkyl(amino)iminates (CAAIs) as strong 2σ,4π-electron donor ligands for the stabilisation of boranes and diboranes(4): a synthetic and computational study
Autor: Silvia Huynh, Merle Arrowsmith, Lukas Meier, Maximilian Dietz, Marcel Härterich, Maximilian Michel, Annalena Gärtner, Holger Braunschweig
Publikováno v: Dalton Transactions. 52:3869-3876
NMR-spectroscopic, structural and theoretical data of cyclic alkyl(amino)iminate (CAAI)-stabilised boranes synthesised by halosilane elimination from CAAI–SiMe3 and haloborane precursors highlight the excellent σ- and π-electron donor ability of
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::c6cc1ff2776cc7787a26313a30c25814
https://doi.org/10.1039/d3dt00298e
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6
On the Reactivity of Phosphaalumenes towards C-C Multiple Bonds
Autor: Samuel Nees, Tim Wellnitz, Fabian Dankert, Marcel Härterich, Simon Dotzauer, Milica Feldt, Holger Braunschweig, Christian Hering‐Junghans
Publikováno v: Angewandte Chemie (International ed. in English).
Heterocycles containing group 13 and 15 elements such as borazines are an integral part of organic, biomedical and materials chemistry. Surprisingly, heterocycles containing P and Al are rare. We have now utilized phosphaalumenes in reactions with al
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::854433e78d6235b5c476eecfcc53b92f
https://pubmed.ncbi.nlm.nih.gov/36516342
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7
Hybrid Inorganic–Organic Cross-Metathesis between Diborenes and Acetylene
Autor: Benedikt Ritschel, Julian Böhnke, Holger Braunschweig, Marcel Härterich, Ashwini K. Phukan, Merle Arrowsmith, Ivo Krummenacher
Publikováno v: Journal of the American Chemical Society. 143:18339-18345
The ruthenium-catalyzed cross-metathesis of alkenes and alkynes, which splits the alkene C═C double bond and couples one-half to each carbon of the alkyne C≡C triple bond, is one of the most efficient tools for the synthesis of 1,3-dienes, with w
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fb60e2ea2ca2ba1cd7e50cd2015317ea
https://doi.org/10.1021/jacs.1c10131
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8
Stepwise reduction of a base-stabilised ferrocenyl aluminium(iii) dihalide for the synthesis of structurally-diverse dialane species
Autor: Debabrata Dhara, Felipe Fantuzzi, Marcel Härterich, Rian D. Dewhurst, Ivo Krummenacher, Merle Arrowsmith, Conor Pranckevicius, Holger Braunschweig
A bulky ferrocenyl-based NHC-stabilised aluminium(iii) dihalide was reduced in different solvents, leading to vastly different outcomes, including formation of a rare example of a dialane and a novel dialuminyl analogue of the Birch reduction.
Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::daf7e5d6e49ffb9d0f14fbd3d7cafa46
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