Zobrazeno 1 - 5
of 5
pro vyhledávání: '"Marcel Ahijado Salomon"'
Publikováno v:
Angewandte Chemie International Edition. 48:1818-1822
Fluorinated building blocks by C-F bond cleavage: Catalytic C-F activation reactions that give novel dioxaborolanes have been developed (see scheme). The reactions proceed at room temperature, and catalytic intermediates are presumably rhodium hydrid
Publikováno v:
Angewandte Chemie. 120:8999-9003
Publikováno v:
Dalton transactions (Cambridge, England : 2003). (38)
A reaction of trans-[Ir(H)(5)(PiPr(3))(2)] (1) with 2,3,5,6-tetrafluoropyridine, pentafluorobenzene or 1,3-difluorobenzene in the presence of neohexene affords the square-pyramidal C-H activation products cis-trans-[Ir(4-C(5)NF(4))(H)(2)(PiPr(3))(2)]
Publikováno v:
Dalton Transactions. :7669
The ammine complexes cis-trans-[Ir(4-C5NF4)(H)2(NH3)(PiPr3)2] (3) and cis-[Ir(4-C5NF4)(H){(E)-(MeO2C)CCH(CO2Me)}(NH3)2(PiPr3)] (5) are generated on reaction of cis-trans-[Ir(4-C5NF4)(H)2(PiPr3)2] (1) or of the vinyl compound trans-[Ir(4-C5NF4)(H){(E)
Publikováno v:
Dalton Transactions: An International Journal of Inorganic Chemistry; Oct2009, Vol. 2009 Issue 37, p7669-7677, 9p