Zobrazeno 1 - 10
of 18
pro vyhledávání: '"Marc T.M. Koper"'
Publikováno v:
Electrochemistry Communications, Vol 166, Iss , Pp 107784- (2024)
In this work, we study the influence of cation concentration and identity on the hydrogen evolution reaction (HER) on polycrystalline platinum (Pt) electrode in pH 3 electrolytes. Our observations indicate that cations in the electrolyte do not affec
Externí odkaz:
https://doaj.org/article/01019a967ff04e4a8146998c60b49cc2
Autor:
Johannes H. Bitter, Matthijs P.J.M. van der Ham, Thom J.P. Hersbach, Juan José Delgado, Marlene Führer, Tomas van Haasterecht, Tiny Verhoeven, Emiel Hensen, Dimosthenis Sokaras, Marc T.M. Koper
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0f1f692aaf7266493b3455cd7b654593
https://doi.org/10.2139/ssrn.4349472
https://doi.org/10.2139/ssrn.4349472
Autor:
Marc T.M. Koper
Publikováno v:
Journal of Electroanalytical Chemistry. 450:189-201
A lattice-gas model is described for the adsorption of halides on single-crystal electrodes. The lateral interactions between the adsorbed halides include a short-range nearest-neighbor interaction and a long-range electrostatic interaction. By Monte
Publikováno v:
Chemical Physics. 220:95-114
The role of nuclear tunneling in adiabatic electrochemical electron-transfer reactions is studied by applying the WKB approximation and the Quantum Kramers Theory to the ground-state potential energy surface calculated from an extended Anderson-Newns
Autor:
Marc T.M. Koper
Publikováno v:
The Journal of Physical Chemistry B. 101:3168-3173
It is shown that for simple electrochemical redox reactions in which both outer- and inner-sphere modes are reorganized, the transfer coefficient α may decrease with increasing temperature if the s...
Autor:
Wolfgang Schmickler, Marc T.M. Koper
Publikováno v:
Chemical Physics. 211:123-133
A simple model for electrochemical ion transfer reactions, based on an extended Anderson-Newns model [W. Schmickler, Chem. Phys. Lett. 237 (1995) 152], is treated within the framework of the multidimensional Kramers theory to calculate ion transfer r
Autor:
Marc T.M. Koper
Publikováno v:
Journal of Electroanalytical Chemistry. 409:175-182
The frequency response or impedance spectrum of an electrochemical cell obtained under potentiostatic conditions can be used to predict the stability features of the electrochemical cell under different electrical conditions, such as galvanostatic co
Autor:
Marc T.M. Koper
Publikováno v:
Berichte der Bunsengesellschaft für physikalische Chemie. 100:497-500
It is shown experimentally that mixed-mode oscillations may be observed in the peroxodisulfate reduction on platinum and gold rotating disk electrodes, in addition to previously reported monoperiodic (relaxation) oscillations. If account is made for
Autor:
Marc T.M. Koper, Tim G.J. Van Venrooij
Publikováno v:
Electrochimica Acta. 40:1689-1696
The occurrence of various sequences of complex bursting and mixed-mode oscillations is described during the hydrogen peroxide reduction on a rotating platinum disk from sulphuric acid solution. It is shown that the current and electrode potential osc
Autor:
Marc T.M. Koper
Publikováno v:
Physica D: Nonlinear Phenomena. 80:72-94