Výsledky vyhledávání - "Marc A. Klingshirn"

Water in Solutions of Chaotropic and Kosmotropic Salts: A Differential Scanning Calorimetry Investigation

Autor: Melanie L. Moody, Jeffrey W. Baldwin, Marc A. Klingshirn, Paula Berton, Jonathan G. Huddleston, Steven P. Kelley, Nicholas J. Bridges, Robin D. Rogers, Heather D. Willauer

Publikováno v: Journal of Chemical & Engineering Data. 64:4781-4792

The use of aqueous phase separations via aqueous biphasic systems (ABS) has been widely explored in the recent decades. For wider and more “intelligent” applications, it is important to look below ...

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::37fb884c335d41c8024f770e888483f5
https://doi.org/10.1021/acs.jced.9b00222

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Kinetic study of the oxidative addition of methyl iodide to Vaska’s complex in ionic liquids

Autor: Steven J. P’Pool, Marc A. Klingshirn, Kevin H. Shaughnessy, Robin D. Rogers

Publikováno v: Journal of Organometallic Chemistry. 690:3522-3528

Oxidative addition of methyl iodide to Vaska’s complex in the ionic liquids 1-butyl-3-methylimidazolium triflate [C4mim][OTf], [C4mim] bis(trifluormethylsulfonyl)imide [Tf2N], and N-hexylpyridinium [C6pyr][Tf2N] occurred cleanly to give the expecte

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::cc8c3c186e4c9cbe496e9274719ff719
https://doi.org/10.1016/j.jorganchem.2005.02.024

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Palladium-catalyzed hydroesterification of styrene derivatives in the presence of ionic liquids

Autor: Marc A. Klingshirn, Kevin H. Shaughnessy, Robin D. Rogers

Publikováno v: Journal of Organometallic Chemistry. 690:3620-3626

The palladium-catalyzed hydroesterification of olefins occurs efficiently in a range of ionic liquid media. Selectivities ranging from 5–7:1 for the linear ester were obtained with styrene in a range of IL solvents. The use of ILs allowed the catal

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::cbe527dc6429ef8f82d07f133350b30e
https://doi.org/10.1016/j.jorganchem.2005.05.031

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Promoting effect of ionic liquids on ligand substitution reactions

Autor: Sidney H. Young, Norris W. Hoffman, Michael D. Sliger, James McNeill, Steven J. P’Pool, Robin D. Rogers, Kevin H. Shaughnessy, Rachel K. Traylor, Marc A. Klingshirn

Publikováno v: Journal of Organometallic Chemistry. 690:3540-3545

Ionic liquid solvents N -hexylpyridinium bistrifylimide ([C 6 pyr][Tf 2 N]] and 1-butyl-3-methylimidazolium hexafluorophosphate ([C 4 mim][PF 6 ]) promoted the displacement of anionic ligands by pyridine derivatives in trans -(Ph 3 P) 2 Rh(CO)NO 3 to

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::02722f2f3620c130becaed2f7a2b39ad
https://doi.org/10.1016/j.jorganchem.2005.02.018

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Gelation of Ionic Liquids Using a Cross-Linked Poly(Ethylene Glycol) Gel Matrix

Autor: Raman Subramanian, Jonathan G. Huddleston, John D. Holbrey, Marc A. Klingshirn, Robin D. Rogers, Scott K. Spear

Publikováno v: Chemistry of Materials. 16:3091-3097

Conductive ionic liquid−poly(ethylene glycol) (IL−PEG) gels have been prepared by gelation of the hydrophobic ionic liquid 1-hexyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide ([C6mim][NTf2]) by the cross-linking reaction of disuccinimi

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::37652a02a201fa093253909ae188738c
https://doi.org/10.1021/cm0351792

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Green chemistry and lanthanide-based crystal engineering

Autor: Marc A. Klingshirn, Grant A. Broker, Robin D. Rogers

Publikováno v: Journal of Alloys and Compounds. 344:123-127

The concept of ‘Green Chemistry’ has received much recent attention due to increased environmental regulations and concerns. This concept is currently being applied to industrial processes as an attempt to help reduce hazardous discharges into th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::2d0b64b7ae7c9e78d019837ed728f667
https://doi.org/10.1016/s0925-8388(02)00349-3

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Polar, non-coordinating ionic liquids as solvents for the alternating copolymerization of styrene and CO catalyzed by cationic palladium catalysts

Autor: Marc A, Klingshirn, Grant A, Broker, John D, Holbrey, Kevin H, Shaughnessy, Robin D, Rogers

Publikováno v: Chemical communications (Cambridge, England). (13)

The palladium-catalyzed copolymerization of styrene and CO in an ionic liquid solvent, 1-hexylpyridinium bis(trifluoromethanesulfonyl)imide, gave improved yields and increased molecular weights compared to polymerizations run in methanol.

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::6184304a150715e475d756e97f952a48
https://pubmed.ncbi.nlm.nih.gov/12125572

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