Photochromic diarylethene ligands featuring 2-(imidazol-2-yl)pyridine coordination site and their iron(II) complexes

Autor: Andrey G. Lvov, Max Mörtel, Anton V. Yadykov, Frank W. Heinemann, Valerii Z. Shirinian, Marat M. Khusniyarov

Publikováno v: Beilstein Journal of Organic Chemistry, Vol 15, Iss 1, Pp 2428-2437 (2019)

A new family of photochromic diarylethene-based ligands bearing a 2-(imidazol-2-yl)pyridine coordination unit has been developed. Four members of the new family have been synthesized. The photoactive ligands feature non-aromatic ethene bridges (cyclo

Externí odkaz: https://doaj.org/article/23ac87dbcbaa4988a06d3c069ed6c9f9

[(thf)5Ln(Ge9{Si(SiMe3)3}2)] (Ln = Eu, Sm, Yb): Capping Metalloid Germanium Cluster with Lanthanides

Autor: Svetlana V. Klementyeva, Kevin Woern, Claudio Schrenk, Minghui Zhang, Marat M. Khusniyarov, Andreas Schnepf

Publikováno v: Inorganic Chemistry. 62:5614-5621

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::d4a5bfada1c067342d1a3eb0bd646ce0
https://doi.org/10.1021/acs.inorgchem.3c00165

One-way photoisomerization of ligands for permanent switching of metal complexes

Autor: Andrey G. Lvov, Max Mörtel, Frank W. Heinemann, Marat M. Khusniyarov

Publikováno v: Journal of Materials Chemistry C. 9:4757-4763

One-way photoisomerization of ligands within metal complexes is an almost unknown phenomenon. We disclosed that a diarylethene-based ligand L-o undergoes quantitative irreversible photoisomerization to a photo- and thermostable annulated isomer L-a b

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::8f7bfd44da44b0de76d44f96a93ab8b3
https://doi.org/10.1039/d1tc00761k

Unusual Dinitrogen Binding and Electron Storage in Dinuclear Iron Complexes

Autor: Keith Searles, Guillaume Gouget, Chun-Hsing Chen, Christopher B. Murray, Kenneth G. Caulton, Marat M. Khusniyarov, Eva M. Zolnhofer, Dieter Sorsche, Daniel J. Mindiola, Matthias E. Miehlich, Patrick J. Carroll, Skye Fortier, Karsten Meyer, Michael R. Gau

Publikováno v: Journal of the American Chemical Society
Journal of the American Chemical Society, American Chemical Society, 2020, 142 (18), pp.8147-8159. ⟨10.1021/jacs.0c01488⟩

A rare example of a dinuclear iron core with a non-linearly bridged dinitrogen ligand is reported in this work. One-electron reduction of [(tBupyrr2py)Fe(OEt2)] (1) (tBupyrr2py2- = 2,6-bis((3,5-di-tert-butyl)pyrrol-2-yl)pyridine) with KC8 yields the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1c84db5f68081207cd6662da25759a37
https://doi.org/10.1021/jacs.0c01488

Molecular Valence Tautomeric Metal Complexes for Chemosensing

Autor: Johannes Oschwald, Marat M. Khusniyarov, Thomas Drewello, Andreas Scheurer, Max Mörtel

Publikováno v: Inorganic chemistry. 60(18)

Switchable valence tautomeric metal complexes have been long suggested for applications as chemosensors. However, no such molecular sensors have been yet reported. Here, we present a concept for sensing and the first prototype molecular sensor based

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f476bb707e2e5368b046eb6f102c7013
https://pubmed.ncbi.nlm.nih.gov/34403241