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Modeling the Geometric, Electronic, and Redox Properties of Iron(III)-Containing Amphiphiles with Asymmetric [NN′O] Headgroups

Autor: Rajendra Shakya, Marco M. Allard, Mary Jane Heeg, Jason Shearer, Bruce R. McGarvey, Eva Rentschler, Cláudio N. Verani, Mara Johann

Publikováno v: Inorganic Chemistry. 50:8356-8366

Two iron(III)-containing amphiphiles 1 and 2 have been synthesized with the [NN'O] ligands HL(tBu-ODA) (2-((octadecyl(pyridin-2-ylmethyl)amino)methyl)-4,6-di-tert-butylphenol) and HL(I-ODA) (2-((octadecyl(pyridin-2-ylmethyl)amino)methyl)-4,6-diiodoph

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a28ef51f7c5acdefbb3bbfb20fbf5eb5
https://doi.org/10.1021/ic2009368

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Hexanuclear copper(ii) cage with {Cu3O⋯H⋯OCu3} core supported by a dicompartmental oxime ligand with m-xylyl spacer: synthesis, molecular structure and magnetic studies

Autor: Subhamoy Ghosh, Sibasree Karmakar, Tapan Kanti Paine, Sumit Khanra, Ennio Zangrando, Thomas Weyhermüller, Mara Johann, Oindrila Das, Eva Rentschler

Publikováno v: Dalton Transactions. 39:10920

A new dicompartmental dioxime ligand (H(2)L) with m-xylyl spacer between the donor sites has been synthesised by Schiff-base condensation of α,α'-diamino-m-xylene and diacetyl monooxime. The ligand reacts with copper(ii) salts giving rise to hexanu

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::11f0bc45b15354c1994d83b7785e76f4
https://doi.org/10.1039/c0dt00951b

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