(Di)triazolylidene manganese complexes in catalytic oxidation of alcohols to ketones and aldehydes

Autor: Mara F. Pinto, Beatriz Royo, Marta Olivares, Ángela Vivancos, Martin Albrecht, Gregorio Guisado-Barrios

Carbonyl manganese complexes with chelating or bridging mesoionic di(1,2,3-triazolylidene) ligands were efficiently synthesised and fully characterised, including the X-ray diffraction study of a bimetallic manganese(0) complex. This unprecedented bi

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Chelating bis-N-heterocyclic carbene complexes of iron(ii) containing bipyridyl ligands as catalyst precursors for oxidation of alcohols

Autor: Mara F. Pinto, Ana M. Martins, Sónia Barroso, Beatriz Royo, Bernardo de P. Cardoso

Publikováno v: Dalton transactions (Cambridge, England : 2003). 45(34)

Chelating bis-N-heterocyclic carbene (bis-NHC) complexes of iron(ii) containing pyridyl ligands have been prepared by the reaction of [FeCl2L] [L = bipy (1), phen (2)] with [LiN(SiMe3)2] and a bis(imidazolium) salt. The [Fe(bis-NHC)L(I)2] complexes w

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https://pubmed.ncbi.nlm.nih.gov/27506414

A Highly Active N-Heterocyclic Carbene Manganese(I) Complex for Selective Electrocatalytic CO 2 Reduction to CO

Autor: Beatriz Royo, Federico Franco, Julio Lloret-Fillol, Mara F. Pinto

Publikováno v: RECERCAT (Dipòsit de la Recerca de Catalunya)
Angewandte Chemie International Edition
Recercat. Dipósit de la Recerca de Catalunya
instname
Recercat: Dipósit de la Recerca de Catalunya
Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)

We report here the first purely organometallic fac-[MnI (CO)3 (bis-Me NHC)Br] complex with unprecedented activity for the selective electrocatalytic reduction of CO2 to CO, exceeding 100 turnovers with excellent faradaic yields (ηCO ≈95 %) in anhy

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