Atmospheric chemistry of 3-methoxy-1-propanol and 3-methoxy-1-butanol: Kinetics with OH radicals and Cl atoms, identification of the end-products in the presence of NO, mechanisms and atmospheric implications

Autor: María de los A. Garavagno, Raúl A. Taccone, Pablo R. Dalmasso, Javier Alejandro Barrera

Publikováno v: Atmospheric Environment. 202:28-40

The rate coefficients for the reactions of OH radicals and Cl atoms with 3-methoxy-1-propanol (3-M-1-POL) and 3-methoxy-1-butanol (3-M-1-BOL) in the gas-phase have been measured at (298 ± 2) K and atmospheric pressure. A conventional relative-rate t

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::f96ae8cb57710cfb6a3f1383edf31a18
https://doi.org/10.1016/j.atmosenv.2018.12.056

Water catalysis of the reaction between hydroxyl radicals and linear saturated alcohols (ethanol and n-propanol) at 294 K

Autor: María de los A. Garavagno, Rafael A. Jara-Toro, Raúl A. Taccone, Gustavo A. Pino, Federico J. Hernández

Publikováno v: Physical Chemistry Chemical Physics
Physical Chemistry Chemical Physics, Royal Society of Chemistry, 2018, 20 (44), pp.27885-27896. ⟨10.1039/c8cp05411h⟩

The rate coefficients for the reactions of OH with ethanol and n-propanol were determined by a relative method in a smog chamber at 294 K, 1 atm of air or N2 and a wide range of humidity. The rate coefficients for both reactions show a quadratic depe

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f56886d6aff3d19108d97b8dd3d645c1
https://doi.org/10.1039/c8cp05411h