Zobrazeno 1 - 10
of 24
pro vyhledávání: '"María V. Alipázaga"'
Publikováno v:
Química Nova, Vol 29, Iss 5, Pp 1086-1093 (2006)
The oxidation of sulfite catalyzed by transition metal ions produces reactive oxysulfur species that can damage plasmid and isolated DNA in vitro. Among the four DNA bases, guanine is the most sensitive to one-electron oxidation promoted by the speci
Externí odkaz:
https://doaj.org/article/d0ff4ae96a1a4773b8e8e892686aee8b
Publikováno v:
Repositório Institucional da USP (Biblioteca Digital da Produção Intelectual)
Universidade de São Paulo (USP)
instacron:USP
Universidade de São Paulo (USP)
instacron:USP
NiIIGGH (GGH, glycylglycyl-L-histidine) reacts rapidly with S(IV), in air-saturated solution, to produce NiIIIGGH. A mechanism is proposed where NiIII oxidizes to , which reacts with dissolved oxygen to produce , initiating radical chain reactions. D
Publikováno v:
Canadian Journal of Chemistry. 85:1064-1069
The voltammetric behavior of the Ni(II)/glycylglycyl-L-histidine complex and the degradation of the electrogenerated Ni(III) species were investigated by cyclic voltammetry. Results of electrochemical and spectrophotometric experiments indicated some
Autor:
Nina Coichev, María V. Alipázaga, Edlaine Linares, Ruben G. M. Moreno, Osmar F. Gomes, Marisa Helena Gennari de Medeiros
Publikováno v:
Journal of Inorganic Biochemistry. 101:866-875
S(IV) (SO(2),HSO(3)(-)andSO(3)(2-)) autoxidation catalyzed by Cu(II)/tetraglycine complexes in the presence of DNA or 2'-deoxyguanosine (dGuo) resulted in DNA strand breaks and formation of 8-oxo-7,8-dihydro-2'-deoxyguanosine (8-oxodGuo), respectivel
Publikováno v:
Química Nova, Vol 29, Iss 5, Pp 1086-1093 (2006)
Química Nova v.29 n.5 2006
Química Nova
Sociedade Brasileira de Química (SBQ)
instacron:SBQ
Química Nova, Volume: 29, Issue: 5, Pages: 1086-1093, Published: OCT 2006
Química Nova v.29 n.5 2006
Química Nova
Sociedade Brasileira de Química (SBQ)
instacron:SBQ
Química Nova, Volume: 29, Issue: 5, Pages: 1086-1093, Published: OCT 2006
The oxidation of sulfite catalyzed by transition metal ions produces reactive oxysulfur species that can damage plasmid and isolated DNA in vitro. Among the four DNA bases, guanine is the most sensitive to one-electron oxidation promoted by the speci
Publikováno v:
Electrochimica Acta. 49:1761-1766
The electrochemistry of Cu(II) in aqueous solutions containing triglycine has been investigated at glassy carbon surfaces. Experiments were carried out at the pH range comprising 7 and 10 and a correlation between the electrochemical behaviour and th
Publikováno v:
Microchimica Acta. 144:57-62
Sulphite was determined in alcoholic (wine) and non-alcoholic (fruit juice) samples using an indirect amperometric FIA method. The current measured at 0 V was proportional to the amount of the Cu3+ species chemically generated by the sulphite-induced
Publikováno v:
Dalton Trans.. :267-272
The oxidation of Ni(II) and Co(II) tetraglycine complexes in borate buffer aqueous solution, by dissolved oxygen, is strongly accelerated by sulfite. The formation of Ni(III) and Co(III) complexes with maximum absorbances at 327 and 265 nm, respectiv
Publikováno v:
Dalton Trans.. :2036-2040
The synergistic effect of Ni(II) and Co(II) on the sulfite induced autoxidation of Cu(II)/tetraglycine was investigated spectrophotometrically at 25.0 degrees C, pH = 9.0, 1 x 10(-5) mol dm(-3)or = [S(IV)]or = 8 x 10(-5) mol dm(-3), [Cu(II)]= 1 x 10(
Autor:
María V. Alipázaga, Nina Coichev
Publikováno v:
Analytical Letters. 36:2255-2275
The present work describes an alternative spectrophotometric method for sulfite determination based on its effect of accelerating the oxidation of Cu(II)/tetraglycine complex by oxygen. The analytical range was (0.5–10)× 10−5 mol L−1 sulfite a