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pro vyhledávání: '"Manuela Schwach"'
Publikováno v:
Chemistry - A European Journal. 2:446-451
The “self-assembly” reaction between bischelating 2,2′-bipyrimidine, metallic copper, Cu2+, and two equivalents of bidentate Ph2P(CH2)nPPh2 produces crystallographically characterized dinuclear complexes with a [Cu1(μ-bpym)-Cu1]2+ core and che
Autor:
Frank Baumann, Manuela Schwach, Michael Moscherosch, Anne-Laure Barra, Louis-Claude Brunel, Wolfgang Kaim
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :3855-3857
Stable, readily accessible and in part even structurally established paramagnetic complex cations [Cu2(µ-η4-BL)L2]+˙, BL = bridging ligand, L = Ph2P(CH2)nPPh2 or 2 PPh3, were studied by high-frequency (245 GHz) and X-band EPR spectroscopy. The dic
Publikováno v:
Inorganic Chemistry. 38:2242-2243
The reaction of Cu, Cu(BF4)2, PPh3, and 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine (bptz) in the appropriate amounts gave the stable radical complex [(Ph3P)2Cu(η4,μ-bptz)Cu(PPh3)2](BF4), whose crystal st...